Novel rhenium(V) oxo complexes containing bis(pyrazol-1-yl)acetate and bis(pyrazol-1-yl) sulfonate as tripodal N,N,O-heteroscorpionate ligands (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Novel rhenium(V) oxo complexes containing bis(pyrazol-1-yl)acetate and bis(pyrazol-1-yl) sulfonate as tripodal N,N,O-heteroscorpionate ligands (Articolo in rivista) (literal)

Anno

• 2005-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/ic050193x (literal)

Alternative label

• Marina Porchia; Grazia Papini; Carlo Santini; Giancarlo Gioia Lobbia; Maura Pellei; Francesco Tisato; Giuliano Bandoli; Alessandro Dolmella (2005)
  Novel rhenium(V) oxo complexes containing bis(pyrazol-1-yl)acetate and bis(pyrazol-1-yl) sulfonate as tripodal N,N,O-heteroscorpionate ligands
  in Inorganic chemistry; ACS, American chemical society, Washington, DC (Stati Uniti d'America)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Marina Porchia; Grazia Papini; Carlo Santini; Giancarlo Gioia Lobbia; Maura Pellei; Francesco Tisato; Giuliano Bandoli; Alessandro Dolmella (literal)

Pagina inizio

• 4045 (literal)

Pagina fine

• 4054 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://pubs.acs.org/doi/pdf/10.1021/ic050193x (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 44 (literal)

Rivista

• Inorganic chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 10 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 11 (literal)

Note

• Scopu (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• ICIS - C.N.R., Padova / Department of Chemical Sciences, University of Camerino / Department of Chemical Sciences, University of Camerino / Department of Chemical Sciences, University of Camerino / Department of Chemical Sciences, University of Camerino / ICIS - C.N.R., Padova / Department of Pharmaceutical Sciences, University of Padova / Department of Pharmaceutical Sciences, University of Padova (literal)

Titolo

• Novel rhenium(V) oxo complexes containing bis(pyrazol-1-yl)acetate and bis(pyrazol-1-yl) sulfonate as tripodal N,N,O-heteroscorpionate ligands (literal)

Abstract

• Reactions of [NBu4][Re(O)Cl4] with bis(pyrazol-1-yl)methane (bpzm), bis(pyrazol-1-yl)acetate (Hbpza) and with the lithium salts Li[bis(3,5-dimethylpyrazol-1-yl)acetate] (Libdmpza), and Li[bis(3,5-dimethylpyrazol-1-yl)methanesulfonate] (Libdmpzs) produce a series of new compounds containing either a k2-N,N bidentate pyrazolyl ligand [Re(O)(bpzm)Cl3 1, Re(O)(bpzm)(OMe)Cl2 2, Re(O)(bpzaOMe)(OMe)Cl2 4] or a k3-N,N,O heteroscorpionate [Re(O)(bpza)Cl2 3, Re(O)(bdmpza)Cl2 isomers 5 and 6, Re(O)(bdmpza)(OMe)Cl 7, Re(O)(bdmpza)(OEt)Cl 8, Re(O)(bdmpzs)(OMe)Cl 9, Re(O)(bdmpzs)(OEt)Cl 10]. X-ray analyses of 1 and 3 show in both cases a distorted octahedral environment around the rhenium atom. The nature and the geometry of the products are strongly determined by the reaction solvent and by the heteroscorpionate ligand itself. When scorpionates bear methylated pyrazolyl rings mixed heterocomplexes Re(O)(bdmpza)(glycol) 11 and Re(O)(bdmpzs)(glycol) 12 are obtained (H2glycol = ethylene glycol). Also 11 shows an octahedral geometry as assessed by X-ray study. (literal)

Editore

• ACS, American chemical society (Editore)

Prodotto di

• Progettazione e sintesi di sistemi molecolari inorganici per diagnosi e terapia (PM.P01.019.002) (Modulo)
• Istituto di chimica inorganica e delle superfici (ICIS) (Istituto)

Autore CNR

• MARINA PORCHIA (Unità di personale interno)
• FRANCESCO TISATO (Persona)

Insieme di parole chiave

• Keywords of "Novel rhenium(V) oxo complexes containing bis(pyrazol-1-yl)acetate and bis(pyrazol-1-yl) sulfonate as tripodal N,N,O-heteroscorpionate ligands" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di chimica inorganica e delle superfici (ICIS) (Istituto)
• Progettazione e sintesi di sistemi molecolari inorganici per diagnosi e terapia (PM.P01.019.002) (Modulo)

Autore CNR di

• MARINA PORCHIA (Unità di personale interno)
• FRANCESCO TISATO (Persona)

Editore di

• ACS, American chemical society (Editore)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganic chemistry (Rivista)

Insieme di parole chiave di

• Keywords of "Novel rhenium(V) oxo complexes containing bis(pyrazol-1-yl)acetate and bis(pyrazol-1-yl) sulfonate as tripodal N,N,O-heteroscorpionate ligands" (Insieme di parole chiave)