Synthesis, structure and properties of new ferrocene-containing compounds (Articolo in rivista)

Type
Label
  • Synthesis, structure and properties of new ferrocene-containing compounds (Articolo in rivista) (literal)
Anno
  • 2003-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/S0020-1693(03)00222-6 (literal)
Alternative label
  • Ossola F. ; Tomasin P.; Benetollo F. ; Foresti E. ; Vigato P.A. (2003)
    Synthesis, structure and properties of new ferrocene-containing compounds
    in Inorganica Chimica Acta (Testo stamp.)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Ossola F. ; Tomasin P.; Benetollo F. ; Foresti E. ; Vigato P.A. (literal)
Pagina inizio
  • 292 (literal)
Pagina fine
  • 300 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://www.sciencedirect.com/science/article/pii/S0020169303002226 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 353 (literal)
Rivista
Note
  • Scopu (literal)
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1,2,3,5 : Ist. Chim. Inorg. e delle Superfici, Area della Ricerca del CNR, Corso Stati Uniti 4, 35127 Padova, Italy / 4 : Dept. of Chemistry 'G. Ciamician', via Selmi 2, 40126 Bologna, Italy (literal)
Titolo
  • Synthesis, structure and properties of new ferrocene-containing compounds (literal)
Abstract
  • The potential use of (aminomethyl)ferrocene and 1,1´-di(aminomethyl)ferrocene as precursor for Schiff base chemistry has been tested. (Aminomethyl)ferrocene reacts with 3,3´-(3-oxapentane-1,5-diyldioxy)bis(2-hydroxybenzaldehyde) to give the [2+1] diiminic ligand 8. 8 reacts with LaCl3 and Ni(CH3COO)2 giving the corresponding complexes 9 and 10. 1,1´-Di(aminomethyl)ferrocene was prepared by conversion of 1,1´-di(formyl)ferrocene into 1,1´-di(formyl)ferrocene oxime, followed by reduction of the oxime with LiAlH4. Easy degradation of 1,1´-di(aminomethyl)ferrocene prevented its use as aminic precursor for the synthesis of Schiff base ligands. Isomerization occurred about the carbon–nitrogen double bonds of 1,1´-di(formyl)ferrocene oxime giving rise to three isomers. The X-ray analysis has shown that in the 5a complex three independent molecules having different conformation are present. (literal)
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