Palladium(II) and platinum(II) complexes of dithiocarbamates and L-methioninol (Articolo in rivista)

Type
Label
  • Palladium(II) and platinum(II) complexes of dithiocarbamates and L-methioninol (Articolo in rivista) (literal)
Anno
  • 2002-01-01T00:00:00+01:00 (literal)
Alternative label
  • Faraglia G., Fedrigo M.A., Sitran S. (2002)
    Palladium(II) and platinum(II) complexes of dithiocarbamates and L-methioninol
    in Transition metal chemistry (Weinh.)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Faraglia G., Fedrigo M.A., Sitran S. (literal)
Pagina inizio
  • 200 (literal)
Pagina fine
  • 206 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 27 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Titolo
  • Palladium(II) and platinum(II) complexes of dithiocarbamates and L-methioninol (literal)
Abstract
  • The [M(dithiocarbamato)(Mol)]Cl complexes [M = Pd or Pt; dithiocarbamato = DMDT (Me2NCS2-) or ESDT (EtO2CCH2MeNCS2-); Mol = L-methioninol (L-2- amino-4-methylthio-1-butanol)] have been prepared by reacting methioninol with the appropriate [M(dithiocarbamato)Cl]n complex at 1 : 1 molar ratio in chlorinated hydrocarbons. By operating at 1 : 2 molar ratio, the binuclear species [M2(dithiocarbamato)2(Mol)Cl2] were obtained. The complexes were characterized by i.r., n.m.r. and electrospray ionisation (ESI) mass spectra and by t.g.a. The [M(dithiocarbamato)(Mol)]Cl species are ionic and contain S,N chelated methioninol. The ligand forms a S,N bridge between two metal atoms in the binuclear species, whose formation is confirmed by the presence of the deprotonated molecular ion in the ESI negative ion mode. (literal)
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