Tailoring the Hydrophobic Character of Mesoporous Silica by Silylation for VOC Removal (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Tailoring the Hydrophobic Character of Mesoporous Silica by Silylation for VOC Removal (Articolo in rivista) (literal)

Anno

• 2010-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1080/01496391003609155 (literal)

Alternative label

• Batonneau-Gener, I; Yonli, A; Trouve, A; Mignard, S; Guidotti, M; Sgobba, M (2010)
  Tailoring the Hydrophobic Character of Mesoporous Silica by Silylation for VOC Removal
  in Separation science and technology (Print); Dekker, New York (Stati Uniti d'America)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Batonneau-Gener, I; Yonli, A; Trouve, A; Mignard, S; Guidotti, M; Sgobba, M (literal)

Pagina inizio

• 768 (literal)

Pagina fine

• 775 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 45 (literal)

Rivista

• Separation science and technology (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 8 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Catalyse Chim Organ Lab, UMR6503, F-86022 Poitiers, France Univ Milan, CNR, Dept Inorgan Chem, Milan, Italy (literal)

Titolo

• Tailoring the Hydrophobic Character of Mesoporous Silica by Silylation for VOC Removal (literal)

Abstract

• MCM-41 and non-ordered mesoporous silica were modified using hexamethyl-disilazane (HMDS). The hydrophobic and hydrophilic properties of grafted materials were studied and compared to a purely all silica BEA zeolite by using competitive and noncompetitive water toluene adsorption. A linear correlation between the silylation degree and the hydrophobicity measurements has been found for MCM-41 materials. Even if highly silylated MCM-41 material have more hydrophilic sites (silanol groups) than all silica zeolite, water molecule condensation is not observed because these sites are isolated. Thus, the highly silylated MCM-41 sample exhibits not only hydrophobicity 2.3 times higher than all silica BEA zeolite but also possesses a storage capacity for toluene and chlorobenzene 3 times higher than this zeolite. In competition with water, the organic molecule (toluene or chlorobenzene) adsorption is always favored even if water adsorption is enhanced by chlorobenzene polarity. (literal)

Editore

• Dekker (Editore)

Prodotto di

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Catalizzatori per la produzione chemo-, regio- e stereoselettiva di fine chemicals (PM.P03.002.002) (Modulo)

Autore CNR

• MATTEO GUIDOTTI (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "Tailoring the Hydrophobic Character of Mesoporous Silica by Silylation for VOC Removal" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Catalizzatori per la produzione chemo-, regio- e stereoselettiva di fine chemicals (PM.P03.002.002) (Modulo)

Autore CNR di

• MATTEO GUIDOTTI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Separation science and technology (Rivista)

Editore di

• Dekker (Editore)

Insieme di parole chiave di

• Parole chiave di "Tailoring the Hydrophobic Character of Mesoporous Silica by Silylation for VOC Removal" (Insieme di parole chiave)