Photophysical properties of metal-mediated assemblies of porphyrins (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Photophysical properties of metal-mediated assemblies of porphyrins (Articolo in rivista) (literal)

Anno

• 2006-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.ccr.2006.01.019 (literal)

Alternative label

• Franco Scandola; Claudio Chiorboli; Anna Prodi; Elisabetta Iengo; Enzo Alessio (2006)
  Photophysical properties of metal-mediated assemblies of porphyrins
  in Coordination chemistry reviews (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Franco Scandola; Claudio Chiorboli; Anna Prodi; Elisabetta Iengo; Enzo Alessio (literal)

Pagina inizio

• 1471 (literal)

Pagina fine

• 1496 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 250 (literal)

Rivista

• Coordination chemistry reviews (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 26 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 11-12 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Dipartimento di Chimica, Universita di Ferrara, 44100 Ferrara, Italy INSTM, Sezione di Ferrara, 44100 Ferrara, Italy ISOF-CNR, Sezione di Ferrara, 44100 Ferrara, Italy Dipartimento di Scienze Chimiche, Universit`a di Trieste, 34127 Trieste, Italy (literal)

Titolo

• Photophysical properties of metal-mediated assemblies of porphyrins (literal)

Abstract

• The metal-driven construction of multi-porphyrin assemblies, which exploits the formation of coordination bonds between peripheral basic site(s) on the porphyrins and metal centers, has recently allowed the design and preparation of sophisticated supramolecular architectures whose complexity and function begin to approach the properties of naturally occurring systems. Within this framework, meso-pyridyl/phenyl porphyrins (PyPs), or strictly related chromophores, can provide geometrically well-defined connections to as many as four metal centers by coordination of the pyridyl peripheral groups. Several discrete assemblies of various nuclearities, in which the pyridylporphyrins are linkers binding metalloporphyrins and/or coordination compounds, have been constructed in recent years. In this review, we summarize recent work from our laboratories on metal-mediated multi-porphyrin assemblies and their photophysical properties. The review is organized as follows: after a brief summary of relevant concepts on energy and electron transfer processes and their implications in charge separation and the antenna effect (Section 2), the main assembling strategies leading to side-to-face and metal-mediated assemblies are synthetically reviewed (Section 3). The photophysical studies leading to the identification and kinetic characterization of the photoinduced energy and/or electron transfer processes within the supramolecular structures are surveyed in Section 4. (literal)

Prodotto di

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Materiali Avanzati per la COnversione di energia Luminosa (MACOL) (PM.P04.010.001) (Modulo)

Autore CNR

• CLAUDIO CHIORBOLI (Unità di personale interno)

Incoming links:

Prodotto

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Materiali Avanzati per la COnversione di energia Luminosa (MACOL) (PM.P04.010.001) (Modulo)

Autore CNR di

• CLAUDIO CHIORBOLI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Coordination chemistry reviews (Rivista)