http://www.cnr.it/ontology/cnr/individuo/prodotto/ID180969
Phase diagram of the Bi4Ti3O12-BaTiO3-(Na1/2Bi1/2)TiO3 system (Articolo in rivista)
- Type
- Label
- Phase diagram of the Bi4Ti3O12-BaTiO3-(Na1/2Bi1/2)TiO3 system (Articolo in rivista) (literal)
- Anno
- 2005-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1111/j.1551-2916.2005.00541.x (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- A. Sanson, R.W.Whatmore (literal)
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- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- CNR-ISTEC, Cranfield University (UK) (literal)
- Titolo
- Phase diagram of the Bi4Ti3O12-BaTiO3-(Na1/2Bi1/2)TiO3 system (literal)
- Abstract
- The phases formed in the ternary system (Na1/2Bi1/2)TiO3-
Bi4Ti3O12-BaTiO3 (NBT-BTO-BT) were studied at 11501C in
air. A very accurate picture of the ternary phase diagram was
obtained examining almost 90 different compositions, exploiting
low-angle XRD analyses to study the layer compounds. New
compounds with five perovskite blocks (m55) were discovered
deep in the phase diagram. No compounds with m45 were
found. It was also established that pure perovskite compounds
can be obtained only at compositions very close to the NBT-BT
line. The relationships between the phases is discussed and it is
hypothesized that the number of perovskite blocks in the system
is determined by charged sites being created by the progressive
substitution of Bi31 in the A site of the perovskite blocks of
BTO with the A cations of the perovskite end-member. (literal)
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- Autore CNR
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