Preparation, characterisation and computational study of poly(epsilon-caprolactone) based nanocomposites (Articolo in rivista)

Type
Label
  • Preparation, characterisation and computational study of poly(epsilon-caprolactone) based nanocomposites (Articolo in rivista) (literal)
Anno
  • 2004-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1179/026708304225022278 (literal)
Alternative label
  • M. Avella, F. Bondioli, V. Cannillo, M. E. Errico, A. M. Ferrari, B. Focher, M. Malinconico, T. Manfredini, M. Montorsi (2004)
    Preparation, characterisation and computational study of poly(epsilon-caprolactone) based nanocomposites
    in Materials science and technology
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • M. Avella, F. Bondioli, V. Cannillo, M. E. Errico, A. M. Ferrari, B. Focher, M. Malinconico, T. Manfredini, M. Montorsi (literal)
Pagina inizio
  • 1340 (literal)
Pagina fine
  • 1344 (literal)
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  • 20 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
  • No. Citazione=8; Autocitazione=3; Motore utilizzato per le citazioni=Google Scholar. (literal)
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  • 5 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 10 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Dipto. Ingegneria Materiali/Ambiente, Universita di Modena e Reggio Emilia, Via Vignolese 9051a, 41100 Modena, Italy Dipto. Sci./Metodi dell'Ingegneria, Universita di Modena e Reggio Emilia, Via Allegri 15, 42100 Reggio Emilia, Italy Ist. Chim./Tecn. Polimeri (ICTP)-CNR, c/o Comprensorio Olivetti, Via Campi Flegrei, 34, 80078 Pozzuoli (Napoli), Italy (literal)
Titolo
  • Preparation, characterisation and computational study of poly(epsilon-caprolactone) based nanocomposites (literal)
Abstract
  • In recent years, scientific and industrial interest has been focused on the preparation of organic/inorganic nanocomposites because of their unique hybrid properties correlated with the enormous interfacial adhesion region that is a characteristic of nanoparticles. The objective of the whole research was to improve poly-caprolactone (PCL) mechanical and barrier performances by using silica spherical nanoparticles for filling. In particular, in order to improve the polymeric matrix/inorganic nanofiller's interfacial adhesion and consequently to achieve a fine nanometric dispersion, silica nanoparticles have been chemically modified by grafting onto them a hydroxyl endcapped PCL, after wheich they have been melt blended with high molecular weight PCL. In the present paper, details on the synthesis, morphology and mechanical properties of the prepared nanocomposites are reported. Moreover, a numerical tool has been used to predict the mechanical properties of the nanocomposite, starting from the morphology of the material observed by scanning electron micrography, and the individual properties of the constituents. (literal)
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