http://www.cnr.it/ontology/cnr/individuo/prodotto/ID178851
Development of molecularly imprinted membranes for selective recognition of primary amines in organic medium (Articolo in rivista)
- Type
- Label
- Development of molecularly imprinted membranes for selective recognition of primary amines in organic medium (Articolo in rivista) (literal)
- Anno
- 2012-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.seppur.2011.11.018 (literal)
- Alternative label
Samuel García Del Blanco, Laura Donato, Enrico Drioli (2012)
Development of molecularly imprinted membranes for selective recognition of primary amines in organic medium
in Separation and purification technology (Online); ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS, AMSTERDAM (Paesi Bassi)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Samuel García Del Blanco, Laura Donato, Enrico Drioli (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Note
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Samuel García Del Blanco: CNR e UNICAL,
Laura Donato: CNR,
Enrico Drioli: CNR e UNICAL (literal)
- Titolo
- Development of molecularly imprinted membranes for selective recognition of primary amines in organic medium (literal)
- Abstract
- Imprinting technique, coupled with membrane technology was used in order to prepare solvent resistant
molecularly imprinted membranes with controlled specificity for the primary aromatic amine 4,40-
methylendianiline. Polyacrylonitrile and its different copolymers such as Poly(acrylonitrile-co-acrylic
acid), Poly(acrylonitrile-co-methacrylic acid) and Poly(acrylonitrile-co-itaconic acid), were selected as
materials to prepare the membranes. The different polymers, were synthesized by the water-phase
precipitation polymerization method and membranes were prepared via the phase inversion technique.
Their recognition properties and separation behaviour for target molecule and other structural analogue
were investigated performing binding experiments in IPA. Results showed that all imprinted membranes
specifically recognize the template in different extent. Imprinted membranes prepared with Poly(acrylonitrile-
co-acrylic acid) were competitive with those prepared using the other two copolymers and exhibited
the highest specific binding capacity towards the template (2.6 lmol/gmemb). In addition, they were
selective with respect to the other primary amine aniline and 4,40-ethylendianiline. On the contrary, Polyacrylonitrile
and blank membranes, showed only a non-specific binding. (literal)
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