Chemoenzymatic Synthesis of Fluorescent and Colored Polyesters (Articolo in rivista)

Type
Label
  • Chemoenzymatic Synthesis of Fluorescent and Colored Polyesters (Articolo in rivista) (literal)
Anno
  • 2011-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/cctc.201000327 (literal)
Alternative label
  • Navarra, Cristina; Marzorati, Mattia; Danieli, Bruno; Riva, Sergio (2011)
    Chemoenzymatic Synthesis of Fluorescent and Colored Polyesters
    in ChemCatChem (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Navarra, Cristina; Marzorati, Mattia; Danieli, Bruno; Riva, Sergio (literal)
Pagina inizio
  • 331 (literal)
Pagina fine
  • 337 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 3 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 7 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 2 (literal)
Note
  • ISI Web of Science (WoS) (literal)
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Ist Chim Riconoscimento Mol; University of Milan (literal)
Titolo
  • Chemoenzymatic Synthesis of Fluorescent and Colored Polyesters (literal)
Abstract
  • A simple chemoenzymatic strategy for the synthesis of colored and fluorescent poly(epsilon-caprolactone) esters has been developed. The procedure involves first the reaction of a functionalized primary amine with epsilon-caprolactone, to give an amide with a terminal primary hydroxy group, followed by an enzymatic ring-opening polymerization catalyzed by Novozym 435. The proposed method is easy to handle and is suitable for the incorporation of different amines, as it shown for the yellow compound N-deacetylthiocolchicine and the fluorescent amines 4-(2-aminoethylamino)-7-(N,N-dimethylsulfamoyl) benzofurazan and dansylcadaverine. A similar strategy is considered for the synthesis of poly(epsilon-caprolactone) esters, employing alcohols as initiators of the reaction. In this case, an intermediate ester carrying a terminal primary hydroxy group cannot be isolated and the reaction forms directly the desired polymers. (literal)
Prodotto di
Autore CNR
Insieme di parole chiave

Incoming links:


Autore CNR di
Prodotto
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
Insieme di parole chiave di
data.CNR.it