Synthesis of L- and D-4,6-Dideoxyhexoses and 4,6-Dideoxy-C-phenylglycosides from Enzyme-Generated Products (Articolo in rivista)

Type
Label
  • Synthesis of L- and D-4,6-Dideoxyhexoses and 4,6-Dideoxy-C-phenylglycosides from Enzyme-Generated Products (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/ejoc.200800662 (literal)
Alternative label
  • Acetti D., Brenna E., Fuganti C., Gatti F.G., Malpezzi L., Serra S. (2008)
    Synthesis of L- and D-4,6-Dideoxyhexoses and 4,6-Dideoxy-C-phenylglycosides from Enzyme-Generated Products
    in European journal of organic chemistry (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Acetti D., Brenna E., Fuganti C., Gatti F.G., Malpezzi L., Serra S. (literal)
Pagina inizio
  • 5125 (literal)
Pagina fine
  • 5134 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR-ICRM Politecnico di Milano (literal)
Titolo
  • Synthesis of L- and D-4,6-Dideoxyhexoses and 4,6-Dideoxy-C-phenylglycosides from Enzyme-Generated Products (literal)
Abstract
  • Optically active 1,3-diols 1 were prepared by biocatalysed routes. The synthetic versatility of compounds 1 as chiral building blocks was shown. The oxidative cleavage of the double bond afforded a carbonyl moiety, which allowed for elongation by Grignard addition and further derivatisation to make deoxy sugars readily available. The epoxidation of the same double bond allowed the direct intramolecular opening of the epoxide ring to generate deoxy C-phenylglycosides. (literal)
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