Synthesis, olfactory evaluation and determination of the absolute configuration of the beta- and gamma-Iralia (R) isomers (Articolo in rivista)

Type
Label
  • Synthesis, olfactory evaluation and determination of the absolute configuration of the beta- and gamma-Iralia (R) isomers (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.tetasy.2008.09.028 (literal)
Alternative label
  • Barakat A., Brenna E., Fuganti C., Serra S. (2008)
    Synthesis, olfactory evaluation and determination of the absolute configuration of the beta- and gamma-Iralia (R) isomers
    in Tetrahedron: asymmetry (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Barakat A., Brenna E., Fuganti C., Serra S. (literal)
Pagina inizio
  • 2316 (literal)
Pagina fine
  • 2322 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 19 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR-ICRM Politecnico di Milano (literal)
Titolo
  • Synthesis, olfactory evaluation and determination of the absolute configuration of the beta- and gamma-Iralia (R) isomers (literal)
Abstract
  • The regioselective synthesis of the methyl-ionone isomers 6-9 is described. The enantiomers of the 7-isomers 8 and 9 are prepared by enzyme-mediated resolution of the corresponding 4-hydroxy derivatives followed by reductive elimination of the hydroxy group. The absolute configuration of the latter compound is determined by chemical correlation with the known alpha-isomers. Since all the isomers obtained are components of the artificial violet odourants sold under the trade name of Iralia (R), their odour properties are evaluated by professional perfumers. (literal)
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