Chemo-enzymatic deracemization methods for the preparation of enantiopure non-natural alpha-amino acids (Articolo in rivista)

Type
Label
  • Chemo-enzymatic deracemization methods for the preparation of enantiopure non-natural alpha-amino acids (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Alternative label
  • Servi S., Tessaro D., Pedrocchi-Fantoni G. (2008)
    Chemo-enzymatic deracemization methods for the preparation of enantiopure non-natural alpha-amino acids
    in Coordination chemistry reviews (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Servi S., Tessaro D., Pedrocchi-Fantoni G. (literal)
Pagina inizio
  • 715 (literal)
Pagina fine
  • 726 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 252 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • ICRM, CNR (literal)
Titolo
  • Chemo-enzymatic deracemization methods for the preparation of enantiopure non-natural alpha-amino acids (literal)
Abstract
  • The complete transformation of a racemate into one single enantiomer is defined as a deracemization. In amino acid chemistry, chemo-enzymatic deracemization is possible due to the ease of racemization of a-amino acids and the numerous enantioselective enzymatic systems operating on this class of compounds. Deracemization by dynamic kinetic resolution is a process in which the enantioselective catalyst is coupled with a second one promoting racemization of the reagent but not of the product. Deracemization by stereo-inversion is a convergent process in which the transformed isomer is finally converted into its enantiomer. These transformations can be applied for the preparation of enantiomerically pure a-amino acids of non-natural configuration or Of L-a-amino acid of non-natural structure. (literal)
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