Incorporation of primary amines into a polyester chain by a combination of chemical and lipase-catalyzed epsilon-caprolactone ring-opening processes (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Incorporation of primary amines into a polyester chain by a combination of chemical and lipase-catalyzed epsilon-caprolactone ring-opening processes (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/adsc.200600642 (literal)

Alternative label

• Marzorati M.; Hult K; Riva S.; Danieli B. (2007)
  Incorporation of primary amines into a polyester chain by a combination of chemical and lipase-catalyzed epsilon-caprolactone ring-opening processes
  in Advanced synthesis & catalysis (Print); Wiley-VCH Verlag Gmbh, Weinheim (Germania)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Marzorati M.; Hult K; Riva S.; Danieli B. (literal)

Pagina inizio

• 1963 (literal)

Pagina fine

• 1968 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://onlinelibrary.wiley.com/doi/10.1002/adsc.200600642/abstract (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 349 (literal)

Rivista

• Advanced synthesis & catalysis (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1 Istituto di Chimica del Riconoscimento Molecolare, C.N.R., Via Mario Bianco 9, 20131 Milano, Italy 2 Dipartimento di Chimica Organica e Industriale, Universit! degli Studi di Milano, Via Venezian 21, 20133 Milano, Italy 3 Department of Biochemistry, Royal Institute of Technology, Stockholm, 10691 Sweden (literal)

Titolo

• Incorporation of primary amines into a polyester chain by a combination of chemical and lipase-catalyzed epsilon-caprolactone ring-opening processes (literal)

Abstract

• A simple chemoenzymatic strategy for the incorporation of bioactive and suitably functionalized molecules into a polyester chain has been developed. The protocol involves first the reaction of a primary amine with ?-caprolactone to give an amide carrying a terminal primary hydroxy group, followed by the enzymatic growth of the polymeric chain triggered by Novozym 435. This method is versatile and easy to handle and is suitable for the incorporation of different amines into polyesters, as has been shown with the model compounds benzylamine and tryptamine, the bioactive compound N-deacetylthiocolchicine and the functionalized propargylamine and tyramine . (literal)

Editore

• Wiley-VCH Verlag Gmbh (Editore)

Prodotto di

• Istituto di chimica del riconoscimento molecolare (ICRM) (Istituto)
• Applicazioni sintetiche della biocatalisi (PM.P03.009.002) (Modulo)

Autore CNR

• SERGIO RIVA (Unità di personale interno)
• MATTIA MARZORATI (Unità di personale esterno)

Insieme di parole chiave

• Keywords of "Incorporation of primary amines into a polyester chain by a combination of chemical and lipase-catalyzed epsilon-caprolactone ring-opening processes" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• SERGIO RIVA (Unità di personale interno)
• MATTIA MARZORATI (Unità di personale esterno)

Prodotto

• Istituto di chimica del riconoscimento molecolare (ICRM) (Istituto)
• Applicazioni sintetiche della biocatalisi (PM.P03.009.002) (Modulo)

Editore di

• Wiley-VCH Verlag Gmbh (Editore)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Advanced synthesis & catalysis (Rivista)

Insieme di parole chiave di

• Keywords of "Incorporation of primary amines into a polyester chain by a combination of chemical and lipase-catalyzed epsilon-caprolactone ring-opening processes" (Insieme di parole chiave)