Short enantioselective synthesis of sedridines, ethylnorlobelols and coniine via reagent-based differentiation (Articolo in rivista)

Type
Label
  • Short enantioselective synthesis of sedridines, ethylnorlobelols and coniine via reagent-based differentiation (Articolo in rivista) (literal)
Anno
  • 2005-01-01T00:00:00+01:00 (literal)
Alternative label
  • Passarella D., Barilli A., Belinghieri F., Fassi P., Riva S., Sacchetti A., Silvani A., Danieli B. (2005)
    Short enantioselective synthesis of sedridines, ethylnorlobelols and coniine via reagent-based differentiation
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Passarella D., Barilli A., Belinghieri F., Fassi P., Riva S., Sacchetti A., Silvani A., Danieli B. (literal)
Pagina inizio
  • 2225 (literal)
Pagina fine
  • 2229 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 16 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Titolo
  • Short enantioselective synthesis of sedridines, ethylnorlobelols and coniine via reagent-based differentiation (literal)
Abstract
  • The preparation of collections of structurally diverse small molecules is a useful tool for studying biology and medicine with chemistry. Herein, we demonstrate the versatility of the pure enantiomers of 2-(2-oxo-ethyl)-piperidine-1-carboxylic acid tertbutyl ester to prepare the biological active alkaloids sedridine, allosedridine, methylsedridine, methylallosedridine, ethylnorlobelol, and coniine in two steps and in a stereoselective way via a reagent-based differentiation. The described syntheses are a demonstration of the versatility of 2-(2-oxo-ethyl)-piperidine-1-carboxylic acid tert-butyl esters as chiral building blocks. (literal)
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