Enantioselective epoxidation of chalcone catalysed by the artificial enzyme poly-L-leucine: kinetic mechanism (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Enantioselective epoxidation of chalcone catalysed by the artificial enzyme poly-L-leucine: kinetic mechanism (Articolo in rivista) (literal)

Anno

• 2004-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.tetasy.2004.06.046 (literal)

Alternative label

• Carrea G., Colonna S., Meek A.D., Ottolina G., Roberts S.M. (2004)
  Enantioselective epoxidation of chalcone catalysed by the artificial enzyme poly-L-leucine: kinetic mechanism
  in Tetrahedron: asymmetry (Print); Pergamon-Elsevier Science Ltd., Oxford (Regno Unito)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Carrea G., Colonna S., Meek A.D., Ottolina G., Roberts S.M. (literal)

Pagina inizio

• 2945 (literal)

Pagina fine

• 2949 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.sciencedirect.com/science/article/pii/S0957416604005361 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 15 (literal)

Rivista

• Tetrahedron: asymmetry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 18 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto di Chimica del Riconoscimento Moleculare, CNR, Via Mario Bianco 9, 20131 Milano, Italy Istituto di Chimica Organica Alessandro Marchesini, Facoltà di Farmacia, via Venezian 21, 20133 Milano, Italy Department of Chemistry, University of Liverpool, Liverpool L69 3BX, UK (literal)

Titolo

• Enantioselective epoxidation of chalcone catalysed by the artificial enzyme poly-L-leucine: kinetic mechanism (literal)

Abstract

• An insight into the kinetics, mechanism and optimum reaction conditions of the Juliá-Colonna enantioselective epoxidation has been gained using a soluble polyleucine catalyst (PLL), chalcone as the substrate, and hydrogen peroxide (HOO-) as the oxidant. PLL shows saturation kinetics for both chalcone and HOO- and has a behaviour that fits a steady state random bireactant system with one of the pathways (HOO- binding first) being kinetically preferred to the other (chalcone binding first) in the formation of the ternary complex PLL:HOO-:Chalcone. (literal)

Editore

• Pergamon-Elsevier Science Ltd. (Editore)

Prodotto di

• Istituto di chimica del riconoscimento molecolare (ICRM) (Istituto)

Autore CNR

• GIANLUCA OTTOLINA (Persona)
• GIACOMO CARREA (Persona)

Insieme di parole chiave

• Parole chiave di "Enantioselective epoxidation of chalcone catalysed by the artificial enzyme poly-L-leucine: kinetic mechanism" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• GIANLUCA OTTOLINA (Persona)
• GIACOMO CARREA (Persona)

Prodotto

• Istituto di chimica del riconoscimento molecolare (ICRM) (Istituto)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Tetrahedron: asymmetry (Rivista)

Editore di

• Pergamon-Elsevier Science Ltd. (Editore)

Insieme di parole chiave di

• Parole chiave di "Enantioselective epoxidation of chalcone catalysed by the artificial enzyme poly-L-leucine: kinetic mechanism" (Insieme di parole chiave)