Dissolution of Candida antarctica lipase B in ionic liquids: effects on structure and activity (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Dissolution of Candida antarctica lipase B in ionic liquids: effects on structure and activity (Articolo in rivista) (literal)

Anno

• 2004-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1039/b405693k (literal)

Alternative label

• Rute Madeira Lau (1); Menno J. Sorgedrager (1); Giacomo Carrea (2); Fred van Rantwijk (1); Francesco Secundo (2); Roger A. Sheldon (1) (2004)
  Dissolution of Candida antarctica lipase B in ionic liquids: effects on structure and activity
  in Green chemistry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Rute Madeira Lau (1); Menno J. Sorgedrager (1); Giacomo Carrea (2); Fred van Rantwijk (1); Francesco Secundo (2); Roger A. Sheldon (1) (literal)

Pagina inizio

• 483 (literal)

Pagina fine

• 487 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 6 (literal)

Rivista

• Green chemistry (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• (1) Laboratory of Biocatalysis and Organic Chemistry, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands. (2) Istituto di Chimica del Riconoscimento Moleculare, CNR, Via Mario Bianco 9, Milano, Italy. (literal)

Titolo

• Dissolution of Candida antarctica lipase B in ionic liquids: effects on structure and activity (literal)

Abstract

• The effects of ionic liquid media on the activity of Candida antarctica lipase B in a simple transesterification reaction were studied. In ionic liquids containing alkylsulfate, nitrate and lactate anions, which dissolved CaLB, the reaction was at least ten times slower than in [BMIm][BF4]. Only [Et3MeN][MeSO4] was an exception, as dissolved CaLB maintained its activity in this solvent. By means of FT-IR spectroscopy, denaturation of CaLB was observed upon dissolution in ionic liquids in which the activity was low, whereas the conformation of enzyme dissolved in [Et3MeN][MeSO4] closely resembled the native one. (literal)

Prodotto di

• Istituto di chimica del riconoscimento molecolare (ICRM) (Istituto)

Autore CNR

• GIACOMO CARREA (Persona)
• FRANCESCO SECUNDO (Persona)

Incoming links:

Prodotto

• Istituto di chimica del riconoscimento molecolare (ICRM) (Istituto)

Autore CNR di

• FRANCESCO SECUNDO (Persona)
• GIACOMO CARREA (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Green chemistry (Rivista)