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Er3+-activated silica inverse opals synthesized by the sol-gel method (Articolo in rivista)
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- Er3+-activated silica inverse opals synthesized by the sol-gel method (Articolo in rivista) (literal)
- Anno
- 2007-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1007/s11801-007-6194-0 (literal)
- Alternative label
A. Chiappini, C. Armellini, A. Chiasera, M. Ferrari, Y. Jestin, E. Moser, M. Montagna, M. Mattarelli, C. Tosello, L. Zampedri,G. Nunzi Conti, S. Pelli, R.M. Almeida, G.C. Righini (2007)
Er3+-activated silica inverse opals synthesized by the sol-gel method
in Optoelectronics Letters (Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- A. Chiappini, C. Armellini, A. Chiasera, M. Ferrari, Y. Jestin, E. Moser, M. Montagna, M. Mattarelli, C. Tosello, L. Zampedri,G. Nunzi Conti, S. Pelli, R.M. Almeida, G.C. Righini (literal)
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- A. Chiappini, E. Moser, M. Montagna, M. Mattarelli, C. Tosello, L. Zampedri - Dipartimento di Fisica, Università di Trento CSMFO group, Via Sommarie 14, 38050 Trento, Italy
C. Armellini, A. Chiasera, M. Ferrari, Y. Jestin - CNR-IFN, Istituto di Fotonica e Nanotecnologie, CSMFO group, Trento, Italy
G. Nunzi Conti, S. Pelli - Photonic Materials and Devices Laboratory, IFAC CNR, 50019 Sesto Fiorentino, Italy
R.M. Almeida - Departamento de Engenharia de Materiais/ICEMS, Instituto Superior Técnico Av. Rovisco Pais, 1049-001 Lisboa, Portugal
G.C. Righini - Department of Materials and Devices, CNR, Piazzale A. Moro 7, 00185 Roma, Italy e CNR-IFAC, 50019 Sesto Fiorentino, Italy (literal)
- Titolo
- Er3+-activated silica inverse opals synthesized by the sol-gel method (literal)
- Abstract
- We present the details of the sol gel processing used to realize inverse silica opal, where the silica was activated with 0.3 mol% of Er3+ ions. The template (direct opal) was obtained assembling polystyrene spheres of the dimensions of 260 nm by means of a vertical deposition technique. The Er3+-activated silica inverse opal was obtained infiltrating, into the void of the template, the silica sol doped with Er3+ ions and subsequently removing the polystyrene spheres by means of calcinations. Scanning electron microscope showed that the inverse opals possess a fcc structure with a air hollows of about 210 nm and a photonic band gap, in the visible range, was observed from reflectance measurements. Spectroscopic properties of Er3+- activated silica inverse opal were investigated by luminescence spectroscopy, where, upon excitation at 514.5 nm, an emission of 4I13/2 ® 4I15/2 of Er3+ ions transition with a 21 nm bandwidth was observed. Moreover the 4I13/2 level decay curve presents a single-exponential profile, with a measured lifetime of 18 ms, corresponding a high quantum efficiency of the system. (literal)
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