Studies on the Lithiation of Hydroxypyrrolidines: Synthesis of Polyhydroxylated Pyrrolidines via Chiral Enecarbamates (Articolo in rivista)

Type
Label
  • Studies on the Lithiation of Hydroxypyrrolidines: Synthesis of Polyhydroxylated Pyrrolidines via Chiral Enecarbamates (Articolo in rivista) (literal)
Anno
  • 2011-01-01T00:00:00+01:00 (literal)
Alternative label
  • Mordini, Alesssandro; Valacchi, Michela; Epiroti, Francesco; Reginato, Gianna; Cicchi, Stefani; Goti Andrea (2011)
    Studies on the Lithiation of Hydroxypyrrolidines: Synthesis of Polyhydroxylated Pyrrolidines via Chiral Enecarbamates
    in Synlett (Stuttg.)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Mordini, Alesssandro; Valacchi, Michela; Epiroti, Francesco; Reginato, Gianna; Cicchi, Stefani; Goti Andrea (literal)
Pagina inizio
  • 235 (literal)
Pagina fine
  • 240 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • ICCOM-CNR Università di Firenze (literal)
Titolo
  • Studies on the Lithiation of Hydroxypyrrolidines: Synthesis of Polyhydroxylated Pyrrolidines via Chiral Enecarbamates (literal)
Abstract
  • The chiral endocyclic enecarbamate 14 has been obtained by deprotonation-elimination from the N-Boc pyrrolidine 5 (or its racemic counterpart from 15). Efficiently stereocontrolled epoxidation-methanolysis of 14 afforded ?-alkoxy carbamates, which undergo completely stereoselective nucleophilic substitutions to give trisubstituted dihydroxypyrrolidines (literal)
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