Study of anisotropic optical properties of poly(arylenephenylene) thin films: dependence on polymer backbone (Articolo in rivista)

Type
Label
  • Study of anisotropic optical properties of poly(arylenephenylene) thin films: dependence on polymer backbone (Articolo in rivista) (literal)
Anno
  • 2003-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/ma0340816 (literal)
Alternative label
  • Losurdo M., Giangregorio M.M., Capezzuto P., Bruno G., Babudri F., Colangiuli D., Farinola G.M., Naso F. M. Losurdo , M.M. Giangregorio ,P. Capezzuto ,G. Bruno ,F. Babudri ,D. Colangiuli ,G.M. Farinola ,F. Naso (2003)
    Study of anisotropic optical properties of poly(arylenephenylene) thin films: dependence on polymer backbone
    in Macromolecules (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Losurdo M., Giangregorio M.M., Capezzuto P., Bruno G., Babudri F., Colangiuli D., Farinola G.M., Naso F. M. Losurdo , M.M. Giangregorio ,P. Capezzuto ,G. Bruno ,F. Babudri ,D. Colangiuli ,G.M. Farinola ,F. Naso (literal)
Pagina inizio
  • 4492 (literal)
Pagina fine
  • 4497 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni
  • The work was undertaken collaboratively with the research group led by Prof. F. Naso, which is well recognized in the field of the synthesis of polymers. IMPACT FACTOR=3.751 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 36 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#descrizioneSinteticaDelProdotto
  • The manuscript is a systematic study of the correlation between structure and optical properties of conjugated polymeric semiconductors using ellipsometric measurements. The work is of interest both to people involved in the synthesis of conjugated polymers, in spectroscopic ellipsometry, and in organic devices optimization. (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • (1)IMIP-CNR, sez. Bari (2)Dept. of Chemistry, Univ of Bari (literal)
Titolo
  • Study of anisotropic optical properties of poly(arylenephenylene) thin films: dependence on polymer backbone (literal)
Abstract
  • The correlation between the optical properties and microstructural parameters of different poly(arylenephenylene) thin films, deposited by spin-coating, is investigated by spectroscopic ellipsometry. Conjugated polymer films are found to be anisotropic. They are birefringent, with a higher refractive index in the plane of the film than perpendicular to it. This anisotropy is due to a preferential in-plane orientation of the polymer chains. The dependence of both the in-plane and out-of-plane optical constants of the polymeric thin films and of the fundamental ð-ð* transition on the structure of the chain backbone are studied. The change of the pi-pi* transition energy of the polymers from solution to thin film and its correlation with the molecular structure are investigated as indicative of interchain interactions. (literal)
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