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Loading silica with metals (palladium or platinum) under mild conditions by using well-defined molecular precursors (Articolo in rivista)
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- Loading silica with metals (palladium or platinum) under mild conditions by using well-defined molecular precursors (Articolo in rivista) (literal)
- Anno
- 2009-01-01T00:00:00+01:00 (literal)
- Alternative label
Armelao, L.; Belli DellAmico, D.; Braglia, R.; Calderazzo, F.; Garbassi, F.; Marra, G.; Merigo, A. (2009)
Loading silica with metals (palladium or platinum) under mild conditions by using well-defined molecular precursors
in Dalton transactions (2003. Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Armelao, L.; Belli DellAmico, D.; Braglia, R.; Calderazzo, F.; Garbassi, F.; Marra, G.; Merigo, A. (literal)
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- Titolo
- Loading silica with metals (palladium or platinum) under mild conditions by using well-defined molecular precursors (literal)
- Abstract
- The loading of pre-treated amorphous silica with platinum or palladium was carried out by using the molecular precursors Pt2(mu-Cl)2Cl2(CO)2, or Pd2(mu-Cl)2Cl2(CO)2, respectively, which contain the required amount of coordinated CO to carry out the formation of the metal particles upon contact with moisture. The reactivity of the well-soluble mononuclear platinum complex cis-PtCl2(CO)2 with stoichiometric amounts of water was investigated either under N2 or CO. The metal nanoparticles produced on the silica matrix have been characterized by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and transmission electron microscopy (TEM). The catalytic performance of the silica-supported metals thus produced was evaluated in the hydrogenation of cyclohexene. (literal)
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