Chemoselective aerobic oxidation of unprotected diols catalyzed by Pd-(NHC) (NHC = N-heterocyclic carbine) complexes (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Chemoselective aerobic oxidation of unprotected diols catalyzed by Pd-(NHC) (NHC = N-heterocyclic carbine) complexes (Articolo in rivista) (literal)

Anno

• 2010-01-01T00:00:00+01:00 (literal)

Alternative label

• Bettucci, Lorenzo; Bianchini, Claudio, Oberhauser, Werner, Hsiao, Tsun-Hung; Lee, Hon Man (2010)
  Chemoselective aerobic oxidation of unprotected diols catalyzed by Pd-(NHC) (NHC = N-heterocyclic carbine) complexes
  in Journal of molecular catalysis. A, Chemical (Online)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Bettucci, Lorenzo; Bianchini, Claudio, Oberhauser, Werner, Hsiao, Tsun-Hung; Lee, Hon Man (literal)

Pagina inizio

• 63 (literal)

Pagina fine

• 72 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 322 (literal)

Rivista

• Journal of molecular catalysis. A, Chemical (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• ICCOM-CNR Department of Chemistry, National Changhua University of Education, 50058 Changhua, Taiwan (literal)

Titolo

• Chemoselective aerobic oxidation of unprotected diols catalyzed by Pd-(NHC) (NHC = N-heterocyclic carbine) complexes (literal)

Abstract

• Neutral Pd(X)(?3-allyl) (X = Cl, OAc (acetate)) complexes bearing mono-coordinating NHC ligands have been synthesized, characterized and employed to catalyze the aerobic oxidation of unprotected 1,2- and 1,3-diols selectively to hydroxy ketones. A comparison of the catalytic performance of these precursors with a reference system has shown that the precursor with the ligands N,N?-bis(adamantyl)imidazol-2- ylidene and chloride is the most efficient for the chemoselective oxidation of 1,2-diols is concerned. Highpressure 1H NMR (HPNMR) experiments in combination with catalytic batch reactions have provided valuable information on the activation of the precursor as well as on the stability of the catalysts. (literal)

Prodotto di

• Catalisi ed elettrocatalisi per la produzione sostenibile di energia e la trasformazione di risorse rinnovabili (PM.P03.001.001) (Modulo)
• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)

Autore CNR

• Lorenzo Bettucci (Persona)
• CLAUDIO BIANCHINI (Persona)
• WERNER OBERHAUSER (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Chemoselective aerobic oxidation of unprotected diols catalyzed by Pd-(NHC) (NHC = N-heterocyclic carbine) complexes" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• Catalisi ed elettrocatalisi per la produzione sostenibile di energia e la trasformazione di risorse rinnovabili (PM.P03.001.001) (Modulo)

Autore CNR di

• CLAUDIO BIANCHINI (Persona)
• WERNER OBERHAUSER (Unità di personale interno)
• Lorenzo Bettucci (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of molecular catalysis. A, Chemical (Rivista)

Insieme di parole chiave di

• Keywords of "Chemoselective aerobic oxidation of unprotected diols catalyzed by Pd-(NHC) (NHC = N-heterocyclic carbine) complexes" (Insieme di parole chiave)