Aqueous rhodium-catalyzed hydroformylation of 1-decene in the presence of randomly methylated b-cyclodextrin and 1,3,5-triaza-7-phosphaadamantane derivatives (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Aqueous rhodium-catalyzed hydroformylation of 1-decene in the presence of randomly methylated b-cyclodextrin and 1,3,5-triaza-7-phosphaadamantane derivatives (Articolo in rivista) (literal)

Anno

• 2009-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.apcata.2009.04.017 (literal)

Alternative label

• Legrand, Francois-X.; Hapiot, Frederic; Tilloy, Sebastien; Guerriero, Antonella; Peruzzini, Maurizio; Gonsalvi, Luca; Monflier, Eric (2009)
  Aqueous rhodium-catalyzed hydroformylation of 1-decene in the presence of randomly methylated b-cyclodextrin and 1,3,5-triaza-7-phosphaadamantane derivatives
  in Applied catalysis. A, General (Print); Elsevier BV, Amsterdam (Paesi Bassi)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Legrand, Francois-X.; Hapiot, Frederic; Tilloy, Sebastien; Guerriero, Antonella; Peruzzini, Maurizio; Gonsalvi, Luca; Monflier, Eric (literal)

Pagina inizio

• 62 (literal)

Pagina fine

• 66 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 362 (literal)

Rivista

• Applied catalysis. A, General (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• ICCOM-CNR; CNRS Lens, France (literal)

Titolo

• Aqueous rhodium-catalyzed hydroformylation of 1-decene in the presence of randomly methylated b-cyclodextrin and 1,3,5-triaza-7-phosphaadamantane derivatives (literal)

Abstract

• The ability of PTA (PTA = 1,3,5-triaza-7-phosphaadamantane) and its N-benzylated derivative (N-Bz- PTA)Cl to interact with the randomly methylated b-cyclodextrin (RAME-b-CD) has been studied by UV- vis and NMR spectroscopies. Both ligands could be considered as non-interacting phosphines with respect to RAME-b-CD. This has been turned to account in a rhodium-catalyzed hydroformylation reaction of 1-decene. A comparison with TPPTS (sodium salt of trisulfonated triphenylphosphine) highlights the beneficial effects of the PTA-based ligands on the chemoselectivity. Actually, chemoselectivities in aldehydes obtained with PTA and (N-Bz-PTA)Cl were very high (>98%) whatever the temperature. Moreover, contrary to what was observed with TPPTS, no decrease in regioselectivity was noticed as the linear to branched aldehydes ratio remains constant. (literal)

Editore

• Elsevier BV (Editore)

Prodotto di

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• Sostenibilità in processi selettivi: catalizzatori, metodologie e approcci innovativi (PM.P03.002.001) (Modulo)

Autore CNR

• MAURIZIO PERUZZINI (Unità di personale interno)
• Antonella Guerriero (Unità di personale esterno)
• LUCA GONSALVI (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "Aqueous rhodium-catalyzed hydroformylation of 1-decene in the presence of randomly methylated b-cyclodextrin and 1,3,5-triaza-7-phosphaadamantane derivatives" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• Sostenibilità in processi selettivi: catalizzatori, metodologie e approcci innovativi (PM.P03.002.001) (Modulo)

Autore CNR di

• LUCA GONSALVI (Unità di personale interno)
• MAURIZIO PERUZZINI (Unità di personale interno)
• Antonella Guerriero (Unità di personale esterno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Applied catalysis. A, General (Rivista)

Editore di

• Elsevier BV (Editore)

Insieme di parole chiave di

• Parole chiave di "Aqueous rhodium-catalyzed hydroformylation of 1-decene in the presence of randomly methylated b-cyclodextrin and 1,3,5-triaza-7-phosphaadamantane derivatives" (Insieme di parole chiave)