Dehydrogenation of cyclohexanol on copper containing catalysts: The role of the support and the preparation method. (Articolo in rivista)

Type
Label
  • Dehydrogenation of cyclohexanol on copper containing catalysts: The role of the support and the preparation method. (Articolo in rivista) (literal)
Anno
  • 2012-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.catcom.2011.10.021 (literal)
Alternative label
  • Popova, M.; Dimitrov, M.; Dal Santo, V.; Ravasio, N.; Scotti, N. (2012)
    Dehydrogenation of cyclohexanol on copper containing catalysts: The role of the support and the preparation method.
    in Catalysis communications (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Popova, M.; Dimitrov, M.; Dal Santo, V.; Ravasio, N.; Scotti, N. (literal)
Pagina inizio
  • 150 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 17 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
  • Scopu (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, 1113, Sofia, Bulgaria Istituto di Scienze e Tecnologie Molecolari (ISTM-CNR), I-20133 Milano, Italy Dept. CIMA “L. Malatesta” University of Milan, Via Venezian 21, 20133, Milano, Italy (literal)
Titolo
  • Dehydrogenation of cyclohexanol on copper containing catalysts: The role of the support and the preparation method. (literal)
Abstract
  • SiO2 and Al2O3 supported copper catalysts were prepared by “chemisorption–hydrolysis” or incipient wetness impregnation methods and investigated by XRD, TG-TPR, UV–vis diffuse reflectance and FTIR spectroscopy. Formation of finely dispersed copper oxide species was registered for the samples prepared by “chemisorption–hydrolysis” method, while a significant amount of XRD detectable copper oxide phase is registered for the SiO2 impregnated one. The latter materials possess higher catalytic selectivity in cyclohexanol dehydrogenation to cyclohexanone. (literal)
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