Evaluation of polymers for conservation treatments of outdoor exposed stone monuments. Part II: Photo-oxidative and salt-induced weathering of acrylic-silicone mixtures (Articolo in rivista)

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Label
  • Evaluation of polymers for conservation treatments of outdoor exposed stone monuments. Part II: Photo-oxidative and salt-induced weathering of acrylic-silicone mixtures (Articolo in rivista) (literal)
Anno
  • 2007-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.polymdegradstab.2006.12.008 (literal)
Alternative label
  • Favaro M.; Mendichi R.; Ossola F.; Simon S.; Tomasin P.; Vigato P.A. (2007)
    Evaluation of polymers for conservation treatments of outdoor exposed stone monuments. Part II: Photo-oxidative and salt-induced weathering of acrylic-silicone mixtures
    in Polymer degradation and stability
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Favaro M.; Mendichi R.; Ossola F.; Simon S.; Tomasin P.; Vigato P.A. (literal)
Pagina inizio
  • 335 (literal)
Pagina fine
  • 351 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://www.sciencedirect.com/science/article/pii/S014139100600351X (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 92 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 3 (literal)
Note
  • ISI Web of Science (WOS) (literal)
  • Scopu (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Istituto di Chimica Inorganica e delle Superfici, CNR, Padova, Italy / Istituto per lo Studio delle Macromolecole, C.N.R / Istituto di Chimica Inorganica e delle Superfici, CNR, Padova, Italy / / Rathgen Forschungslabor - Staatliche Museen zu Berlin, Schloßstraße 1A, D-14059 Berlin, Germany Istituto di Chimica Inorganica e delle Superfici, CNR, Padova, Italy / Istituto di Chimica Inorganica e delle Superfici, CNR, Padova, Italy (literal)
Titolo
  • Evaluation of polymers for conservation treatments of outdoor exposed stone monuments. Part II: Photo-oxidative and salt-induced weathering of acrylic-silicone mixtures (literal)
Abstract
  • acrylic-silicone mixture, stone conservation, photo-oxidative and saline solution ageing, acrylic carboxylate salts (literal)
  • The behaviour of the acrylic-silicone mixture commonly known as Bologna Cocktail, composed of commercial acrylic polymer Paraloid B72 and the silicon-based product, Dri-film 104, extensively employed as stone preservative for monuments in the last thirty years, has been tested on specimens appropriately prepared and submitted to ageing simulating reliable outdoor environment. After chemical characterization, the acrylic-silicone mixture was applied as thin film on slides, as thick film on Petri dishes and on marble by brush or by imbibition; the resulting samples were artificially aged by light and saline solution. The chemical modifications were evaluated by FT-IR, NMR and SEC determinations, while preservative properties were tested by removability tests, ultrasonic and colorimetric measurements. The mixture consists of two immiscible phases and the two components have distinctive chemical behaviours, leading - after ageing - to irreversible molecular modifications and loss of conservative properties. The deterioration processes identified through laboratory simulation have been also verified on treated marble surfaces of two Venetian case studies. (literal)
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