http://www.cnr.it/ontology/cnr/individuo/prodotto/ID168738
Electrodeposition of Cu+PdO and (Cu-Pd)+PdO Composites (Articolo in rivista)
- Type
- Label
- Electrodeposition of Cu+PdO and (Cu-Pd)+PdO Composites (Articolo in rivista) (literal)
- Anno
- 2010-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1149/1.3310021 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Enrico Verlato; Sandro Cattarin; Nicola Comisso; Rosalba Gerbasi; Paolo Guerriero; Marco Musiani; Lourdes Vázquez-Gómez (literal)
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- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
- http://scitation.aip.org/getabs/servlet/GetabsServlet?prog=normal&id=JESOAN00015700000400D248000001&idtype=cvips&gifs=yes&ref=no (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
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- ISI Web of Science (WOS) (literal)
- Scopu (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- 1,2,3,6,7: Istituto per l'Energetica e le Interfasi (IENI) CNR, Corso Stati Uniti 4, 35127 Padova, Italy /
4,5: Istituto di Chimica Inorganica e delle Superfici (ICIS) - CNR, Corso Stati Uniti 4, 35127 Padova, Italy (literal)
- Titolo
- Electrodeposition of Cu+PdO and (Cu-Pd)+PdO Composites (literal)
- Abstract
- The codeposition of PdO particles with a Cu matrix has been investigated with the aim of extending the composite deposition procedure to the preparation of materials potentially capable of catalyzing the low temperature combustion of methane. Cu + PdO composites with a low dispersed phase content were obtained from either basic pyrophosphate or acid sulfate baths.
Codeposition of PdO particles with a CuPd alloy matrix was effectively achieved by electrolyzing suspensions of PdO in solutions containing both Cu2+ and Pd2+ ions, with large (Cu2+)/(Pd2+) ratios. (CuPd) + PdO deposits with 2025 Pd atom % were obtained in which only 12 atom % of Pd were alloyed in the matrix. These (CuPd) + PdO composites were mechanically stable and highly porous throughout their thickness (their pore volume being ca. 60% of the total volume). Their true surface area was some thousands of times higher than their geometric area. (literal)
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