Mononuclear ruthenium complexes containing two different phosphines in trans position: II Catalytic hydrogenation of C=C and C=O bonds (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Mononuclear ruthenium complexes containing two different phosphines in trans position: II Catalytic hydrogenation of C=C and C=O bonds (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.jorganchem.2006.11.036 (literal)

Alternative label

• Salvi, Luca; Salvini, Antonella; Micoli, Francesca; Bianchini, Claudio; Oberhauser, Werner (2007)
  Mononuclear ruthenium complexes containing two different phosphines in trans position: II Catalytic hydrogenation of C=C and C=O bonds
  in Journal of organometallic chemistry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Salvi, Luca; Salvini, Antonella; Micoli, Francesca; Bianchini, Claudio; Oberhauser, Werner (literal)

Pagina inizio

• 1442 (literal)

Pagina fine

• 1450 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 692 (literal)

Rivista

• Journal of organometallic chemistry (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• ICCOM-CNR Department of Organic Chemistry, University of Florence, 50019 Sesto Fiorentino, Italy (literal)

Titolo

• Mononuclear ruthenium complexes containing two different phosphines in trans position: II Catalytic hydrogenation of C=C and C=O bonds (literal)

Abstract

• Bis(acetate) ruthenium(II) complexes of the general formula Ru(CO)2(OAc)2(PnBu3)[P(p-XC6H4)3] (OAc = acetate, X = CH3O, CH3, H, F or Cl), containing different phosphine ligands trans to PnBu3, have been employed as catalyst precursors for the hydrogenation of 1- hexene, acetophenone, 2-butanone and benzylideneacetone. For comparative purposes, analogous reactions have been performed using the homodiphosphine precursors Ru(CO)2(OAc)2(PnBu3)2 and Ru(CO)2(OAc)2(PPh3)2. The catalytic activity of the heterodiphosphine complexes depends on the basicity of the triarylphosphine trans to PnBu3 as this factor controls, inter alia, the rate of formation of hydride(acetate), Ru(CO)2(H)(OAc)(PnBu3)[P(p-XC6H4)3], or dihydride, Ru(CO)2(H)2(PnBu3)[(p-XC6H4)3], complexes, by hydrogenation of the bis(OAc) precursors. The catalytic hydrogenation of the C@C double bond is best accomplished by homodiphosphine dihydride catalysts, while heterodiphosphine monohydrides are more efficient catalysts than the homo- and heterodiphosphine dihydrides for the reduction of the keto C@O bond. (literal)

Prodotto di

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• prodotti di valorizzazione del glicerolo (PM.P03.004.001) (Modulo)

Autore CNR

• CLAUDIO BIANCHINI (Persona)
• WERNER OBERHAUSER (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Mononuclear ruthenium complexes containing two different phosphines in trans position: II Catalytic hydrogenation of C=C and C=O bonds" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• prodotti di valorizzazione del glicerolo (PM.P03.004.001) (Modulo)

Autore CNR di

• CLAUDIO BIANCHINI (Persona)
• WERNER OBERHAUSER (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of organometallic chemistry (Rivista)

Insieme di parole chiave di

• Keywords of "Mononuclear ruthenium complexes containing two different phosphines in trans position: II Catalytic hydrogenation of C=C and C=O bonds" (Insieme di parole chiave)