CO-ethylene copolymerization reactions in different reaction media catalyzed by palladium(II) complexes with chelating diphosphines bearing ortho-methoxy-substituted aryl groups (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• CO-ethylene copolymerization reactions in different reaction media catalyzed by palladium(II) complexes with chelating diphosphines bearing ortho-methoxy-substituted aryl groups (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.molcata.2006.10.035 (literal)

Alternative label

• Bianchini, Claudio; Meli, Andrea; Oberhauser, Werner; Segarra, Anna Maria; Claver, Carmen; Garcia Suarez, Eduardo J. (2007)
  CO-ethylene copolymerization reactions in different reaction media catalyzed by palladium(II) complexes with chelating diphosphines bearing ortho-methoxy-substituted aryl groups
  in Journal of molecular catalysis. A, Chemical (Online)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Bianchini, Claudio; Meli, Andrea; Oberhauser, Werner; Segarra, Anna Maria; Claver, Carmen; Garcia Suarez, Eduardo J. (literal)

Pagina inizio

• 292 (literal)

Pagina fine

• 305 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 265 (literal)

Rivista

• Journal of molecular catalysis. A, Chemical (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• ICCOM-CNR Universitat Rovira i Virgili, Tarragona, Spain (literal)

Titolo

• CO-ethylene copolymerization reactions in different reaction media catalyzed by palladium(II) complexes with chelating diphosphines bearing ortho-methoxy-substituted aryl groups (literal)

Abstract

• Neutral and bis-cationic palladium(II) complexes with 1,2-bis(di(2-methoxyphenyl)phosphino)ethane (o-MeO-dppe) and 1,3-bis(di(2- methoxyphenyl)phosphino)propane (o-MeO-dppp) have been synthesized and employed to catalyze the CO-ethylene copolymerization reaction in either protic or aprotic solvents. A comparison of the catalytic performance of these complexes with that of analogous precursors stabilized by 1,2-bis(diphenylphosphino)ethane (dppe) and 1,3-bis(diphenylphosphino)propane (dppp) ligands has shown significant differences in terms of catalytic productivity and molecular weight. In situ and operando high-pressure NMR experiments have provided valuable information on catalysis resting states and intermediates and have contributed to rationalize the observed productivity as well. (literal)

Prodotto di

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• prodotti di valorizzazione del glicerolo (PM.P03.004.001) (Modulo)

Autore CNR

• CLAUDIO BIANCHINI (Persona)
• WERNER OBERHAUSER (Unità di personale interno)
• ANDREA MELI (Persona)

Insieme di parole chiave

• Keywords of "CO-ethylene copolymerization reactions in different reaction media catalyzed by palladium(II) complexes with chelating diphosphines bearing ortho-methoxy-substituted aryl groups" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• prodotti di valorizzazione del glicerolo (PM.P03.004.001) (Modulo)

Autore CNR di

• CLAUDIO BIANCHINI (Persona)
• WERNER OBERHAUSER (Unità di personale interno)
• ANDREA MELI (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of molecular catalysis. A, Chemical (Rivista)

Insieme di parole chiave di

• Keywords of "CO-ethylene copolymerization reactions in different reaction media catalyzed by palladium(II) complexes with chelating diphosphines bearing ortho-methoxy-substituted aryl groups" (Insieme di parole chiave)