Ligand effects in the non-alternating CO-ethylene copolymerization by palladium(II) catalysis (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Ligand effects in the non-alternating CO-ethylene copolymerization by palladium(II) catalysis (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1039/b711280g (literal)

Alternative label

• Bettucci L.; Bianchini C.; Claver C.; Garcia Suarez E. J.; Ruiz A.; Meli A.; Oberhauser W. (2007)
  Ligand effects in the non-alternating CO-ethylene copolymerization by palladium(II) catalysis
  in Dalton transactions (2003. Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Bettucci L.; Bianchini C.; Claver C.; Garcia Suarez E. J.; Ruiz A.; Meli A.; Oberhauser W. (literal)

Pagina inizio

• 5590 (literal)

Pagina fine

• 5602 (literal)

Rivista

• Dalton transactions (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto di Chimica deiComposti Organometallici (ICCOM-CNR),Area di RicercaCNRdi Firenze, viaMadonna delPiano 10, 50019, Sesto Fiorentino, Italy. Dept. de Quimica Fisica i Inorganica, Facultat de Quimica, Universitat Rovira i Virgili, c/Marcel.li Domingo s/n, 43007, Tarragona, Spain. (literal)

Titolo

• Ligand effects in the non-alternating CO-ethylene copolymerization by palladium(II) catalysis (literal)

Abstract

• In this paper we report on a comparative study of the non-alternating CO-C2H4 copolymerization catalyzed by neutral PdII complexes with the phosphine-sulfonate ligands bis(o-methoxyphenyl)- phosphinophenylenesulfonate and bis(o-methoxyphenyl)phosphino-ethylenesulfonate. The former ligand, featuring a lower skeletal flexibility, has been found to form more active catalysts as well as produce polyketones with higher molecular weight and higher extra-ethylene incorporation. Operando high-pressure NMR studies have allowed us to intercept, for the first time, PdII(phosphine-sulfonate) b-chelates in the non-alternating copolymerization cycle, while model organometallic reactions have contributed to demonstrate that PdII (phosphine-sulfonate) fragments do not form stable carbonyl complexes. The opening of the b-chelates has been found to be a viable process by either comonomer, which contrasts with the behaviour of PdII (chelating diphosphine) catalysts for the perfectly alternating copolymerization (literal)

Prodotto di

• prodotti di valorizzazione del glicerolo (PM.P03.004.001) (Modulo)
• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)

Autore CNR

• ANDREA MELI (Persona)
• CLAUDIO BIANCHINI (Persona)
• WERNER OBERHAUSER (Unità di personale interno)
• Lorenzo Bettucci (Persona)

Incoming links:

Prodotto

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• prodotti di valorizzazione del glicerolo (PM.P03.004.001) (Modulo)

Autore CNR di

• CLAUDIO BIANCHINI (Persona)
• WERNER OBERHAUSER (Unità di personale interno)
• ANDREA MELI (Persona)
• Lorenzo Bettucci (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Dalton transactions (Rivista)