Study of the [Fe(OMe)(dpm)2]2 dimer in the presence of a magnetic field by using Mössbauer spectroscopy (Articolo in rivista)

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  • Study of the [Fe(OMe)(dpm)2]2 dimer in the presence of a magnetic field by using Mössbauer spectroscopy (Articolo in rivista) (literal)
Anno
  • 2006-01-01T00:00:00+01:00 (literal)
Alternative label
  • Cianchi, L; Del Giallo, F; Lantieri, M; Moretti, P; Spina, G (2006)
    Study of the [Fe(OMe)(dpm)2]2 dimer in the presence of a magnetic field by using Mössbauer spectroscopy
    in Hyperfine interactions
    (literal)
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  • Cianchi, L; Del Giallo, F; Lantieri, M; Moretti, P; Spina, G (literal)
Pagina inizio
  • 1115 (literal)
Pagina fine
  • 1119 (literal)
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  • 168 (literal)
Rivista
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  • fasc. (1-3). Springer. Reprinted in ICAME 2005, 2007, Part 67. (literal)
Note
  • ISI Web of Science (WOS) (literal)
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  • CNR, Ist Sistemi Complessi, I-50019 Sesto Fiorentino, FI, Italy; Univ Florence, Dipartimento Chim, I-50019 Sesto Fiorentino, FI, Italy; Univ Florence, Dipartimento Fis, INFM, I-50019 Sesto Fiorentino, FI, Italy (literal)
Titolo
  • Study of the [Fe(OMe)(dpm)2]2 dimer in the presence of a magnetic field by using Mössbauer spectroscopy (literal)
Abstract
  • We present a Mossbauer study of a S = 0 ground state magnetic Fe(III)-dimer in the presence of an applied 5 T longitudinal magnetic field, between 7.6 and 33 K. The values obtained for the isomer shift and the quadrupolar splitting are comparable with the ones of Fe(III) ions coordinated to eight oxygen ions. Regarding the spin dynamics, both intramultiplet and intermultiplet transitions are considered. In the chosen temperature range the rate of the former transitions is constant, within the errors, while the rate of the latter ones quickly increases with the temperature. (literal)
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