Methoxycarbonylation of Styrene to Methyl Arylpropanoates Catalyzed by Palladium(II) Precursors with 1,1’-Bis(diphenylphosphino)metallocenes (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Methoxycarbonylation of Styrene to Methyl Arylpropanoates Catalyzed by Palladium(II) Precursors with 1,1’-Bis(diphenylphosphino)metallocenes (Articolo in rivista) (literal)

Anno

• 2004-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.molcata.2004.06.029 (literal)

Alternative label

• Bianchini, Claudio; Meli, Andrea; Oberhauser, Werner; Parisel, Sebastien; Gusev, Oleg V.; Kal’sin, Alexander M.; Vologdin, Nikolai V.; Dolgushin, Fedor M. (2004)
  Methoxycarbonylation of Styrene to Methyl Arylpropanoates Catalyzed by Palladium(II) Precursors with 1,1’-Bis(diphenylphosphino)metallocenes
  in Journal of molecular catalysis. A, Chemical (Online)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Bianchini, Claudio; Meli, Andrea; Oberhauser, Werner; Parisel, Sebastien; Gusev, Oleg V.; Kal’sin, Alexander M.; Vologdin, Nikolai V.; Dolgushin, Fedor M. (literal)

Pagina inizio

• 35 (literal)

Pagina fine

• 49 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 224 (literal)

Rivista

• Journal of molecular catalysis. A, Chemical (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• ICCOM-CNR Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Vavilov, 119991 Moscow, Russia (literal)

Titolo

• Methoxycarbonylation of Styrene to Methyl Arylpropanoates Catalyzed by Palladium(II) Precursors with 1,1’-Bis(diphenylphosphino)metallocenes (literal)

Abstract

• Palladium(II) complexes with 1,1?-bis(diphenylphosphino)ferrocene (dppf), 1,1?-bis(diphenylphosphino)octamethylferrocene (dppomf), 1,1?-bis(diphenylphosphino)ruthenocene (dppr) and 1,1?-bis(diphenylphosphino)osmocene (dppo) have been synthesized and used to catalyze the methoxycarbonylation of styrene. Irrespective of the precursor, all the reactions gave methyl phenylpropanoates with prevalence of the linear isomer methyl 3-phenylpropanoate (up to 85% regioselectivity). The highest turnover frequency was obtained with the dppr precursor in the presence of p-toluenesulphonic acid co-catalyst (334 mol of styrene converted (mol of catalyst h)-1). A reaction mechanism accounting for both activity and selectivity has been proposed on the basis of operando high-pressure NMR experiments and reactions with model compounds. (literal)

Prodotto di

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• prodotti di valorizzazione del glicerolo (PM.P03.004.001) (Modulo)

Autore CNR

• CLAUDIO BIANCHINI (Persona)
• WERNER OBERHAUSER (Unità di personale interno)
• ANDREA MELI (Persona)
• SEBASTIEN PARISEL (Unità di personale esterno)

Insieme di parole chiave

• Parole chiave di "Methoxycarbonylation of Styrene to Methyl Arylpropanoates Catalyzed by Palladium(II) Precursors with 1,1’-Bis(diphenylphosphino)metallocenes" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• prodotti di valorizzazione del glicerolo (PM.P03.004.001) (Modulo)

Autore CNR di

• CLAUDIO BIANCHINI (Persona)
• WERNER OBERHAUSER (Unità di personale interno)
• ANDREA MELI (Persona)
• SEBASTIEN PARISEL (Unità di personale esterno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of molecular catalysis. A, Chemical (Rivista)

Insieme di parole chiave di

• Parole chiave di "Methoxycarbonylation of Styrene to Methyl Arylpropanoates Catalyzed by Palladium(II) Precursors with 1,1’-Bis(diphenylphosphino)metallocenes" (Insieme di parole chiave)