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Thermal decomposition of mixed Ce and Gd oxalates and thermal properties of mixed Ce and Gd oxides (Articolo in rivista)

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Thermal decomposition of mixed Ce and Gd oxalates and thermal properties of mixed Ce and Gd oxides (Articolo in rivista) (literal)

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Alternative label

Ubaldini A., Artini C., Costa G. A., Carnasciali M.M., Masini R. (2006)
Thermal decomposition of mixed Ce and Gd oxalates and thermal properties of mixed Ce and Gd oxides
in Journal of thermal analysis and calorimetry (Dordr., Online); SPRINGER, DORDRECHT (Paesi Bassi)
(literal)

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INFM and DCCI, I-16146 Genoa, Italy; INFM and DCCI, I-16146 Genoa, Italy; INFM and DCCI, I-16146 Genoa, Italy; INSTM and DCCI, I-16146 Genoa, Italy; CNR-IMEM, Via Dodecaneso 33, 16146 Genova, Italy (literal)

Titolo

Thermal decomposition of mixed Ce and Gd oxalates and thermal properties of mixed Ce and Gd oxides (literal)

Abstract

The aim of the present work is to study the thermal decomposition of the mixed oxalates (Ce1-xGdx)(2)(C2O4)(3)center dot nH(2)O. The mechanisms of decomposition of Ce and Gd oxalate are different, and mixed oxalates behave in-an intermediate way. Their dehydration stages are more similar to those of Gd oxalate, as not all the molecules of water are equivalent like the cerium oxalate. The decomposition leads to (Ce1-xGdx)O2-x/2. For x close to 0 or to 1 two solid solutions exist, while for the central composition, the presence of a biphasic region can not be excluded. (literal)

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