Synthesis, Characterization and Reactivity of 1,1'-Bis(diphenylphosphino)osmocene: Palladium(II) Complexes and Their Use as Catalysts in the Methoxycarbonylation of Olefins (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Synthesis, Characterization and Reactivity of 1,1'-Bis(diphenylphosphino)osmocene: Palladium(II) Complexes and Their Use as Catalysts in the Methoxycarbonylation of Olefins (Articolo in rivista) (literal)

Anno

• 2003-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/om0208366 (literal)

Alternative label

• Gusev, Oleg V.; Kalsin, Alexander M.; Petrovskii, Pavel V.; Lyssenko, Konstantin A.; Oprunenko Yuri F.; Bianchini Claudio; Meli, Andrea; Oberhauser, Werner (2003)
  Synthesis, Characterization and Reactivity of 1,1'-Bis(diphenylphosphino)osmocene: Palladium(II) Complexes and Their Use as Catalysts in the Methoxycarbonylation of Olefins
  in Organometallics
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Gusev, Oleg V.; Kalsin, Alexander M.; Petrovskii, Pavel V.; Lyssenko, Konstantin A.; Oprunenko Yuri F.; Bianchini Claudio; Meli, Andrea; Oberhauser, Werner (literal)

Pagina inizio

• 913 (literal)

Pagina fine

• 915 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 22 (literal)

Rivista

• Organometallics (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• 0,0,0 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• ICCOM-CNR Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Vavilov, Moscow, Russian Federation (literal)

Titolo

• Synthesis, Characterization and Reactivity of 1,1'-Bis(diphenylphosphino)osmocene: Palladium(II) Complexes and Their Use as Catalysts in the Methoxycarbonylation of Olefins (literal)

Abstract

• The synthesis and characterization of 1,1’-bis(diphenylphosphino)osmocene (dppo) is presented. This new ligand forms a variety of palladium(II) complexes showing either k2-P,P or k3-Os,P,P bonding mode. A single-crystal X-ray analysis of [Pd(NCMe)(dppo)](OTf)2 (OTf = trifluoromethanesulfonate) shows the palladium center to be square-planarly coordinated by osmium, two trans phosphorus atoms, and h1-N-MeCN. The complex [Pd(OTs)(dppo)]OTs (OTs = p-toluenesulfonate) is an effective catalyst precursor for the selective methoxycarbonylation of ethylene to methyl propanoate and of styrene to a mixture of methyl 3-phenylpropanoate and methyl 2-phenylpropanoate. (literal)

Prodotto di

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)

Autore CNR

• ANDREA MELI (Persona)
• CLAUDIO BIANCHINI (Persona)
• WERNER OBERHAUSER (Unità di personale interno)

Incoming links:

Prodotto

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)

Autore CNR di

• CLAUDIO BIANCHINI (Persona)
• WERNER OBERHAUSER (Unità di personale interno)
• ANDREA MELI (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Organometallics (Rivista)