First true square-planar Hg(II) compound: synthesis and full characterization of trans-(Hg(Ph2PNP(O)Ph2-P,O)2 (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• First true square-planar Hg(II) compound: synthesis and full characterization of trans-(Hg(Ph2PNP(O)Ph2-P,O)2 (Articolo in rivista) (literal)

Anno

• 2003-01-01T00:00:00+01:00 (literal)

Alternative label

• Haid, Rainer; Gutmann, Rene; Czermak, Georg; Langes, Christoph; Oberhauser, Werner; Kopacka, Holger; Ongania, Karl-Hans; Brueggeller, Peter (2003)
  First true square-planar Hg(II) compound: synthesis and full characterization of trans-(Hg(Ph2PNP(O)Ph2-P,O)2
  in Inorganic chemistry communications
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Haid, Rainer; Gutmann, Rene; Czermak, Georg; Langes, Christoph; Oberhauser, Werner; Kopacka, Holger; Ongania, Karl-Hans; Brueggeller, Peter (literal)

Pagina inizio

• 61 (literal)

Pagina fine

• 67 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 6 (literal)

Rivista

• Inorganic chemistry communications (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• ICCOM-CNR Institut fuer Allgemeine, Anorganische und Theoretische Chemie, Universitaet Innsbruck, Innrain 52a, 6020 Innsbruck, Austria (literal)

Titolo

• First true square-planar Hg(II) compound: synthesis and full characterization of trans-(Hg(Ph2PNP(O)Ph2-P,O)2 (literal)

Abstract

• The reaction of HgðO3SCF3Þ2 with bis(diphenylphosphino)amine, Ph2PNHPPh2 (dppam), produces the novel, rare face-to-face complex ½Hg2ðO3SCF3Þ4ðdppamÞ2? (1). Treatment of 1 with Na2N2O3 leads to trans-½HgfPh2PNPðOÞPh2-P;Og2? (2) via regioselective oxidation and simultaneous deprotonation of dppam. 2 is the first true square-planar Hg(II) compound. In 2 the coordination plane and the five-membered rings of the HgNOP2 moieties are completely coplanar indicating strong p-bonding interactions. Both 1 and 2 have been fully characterized by X-ray structure analyses, NMRspectroscopy ð199Hgf1Hg; 31Pf1Hg; 13Cf1Hg; 1HÞ, ESI and FAB mass spectrometry, IRspectroscopy, elemental analyses, and melting points. Since in Hg(II) compounds relativistic effects favour linear coordination and Hg(II) donor atom preferences play a significant role, the Hg-P bond length of 2.4042(7) ?AA in 2 is short, whereas the Hg-O bond length of 2.7138(15) ?AA is long. In view of the X-ray structures of 1 and 2, it is shown that the delocalized charge in ½Ph2PNPðOÞPh2?? is responsible for the achievement of the squareplanar coordination in a Hg(II) compound. A similar p-bonding effect has been observed in several square-planar complexes of Pt(II), Pd(II), and Ni(II) containing cis-1,2-bis(diphenylphosphino)ethene (cis-dppen). (literal)

Prodotto di

• Institute of chemistry of organometallic compounds (ICCOM) (Istituto)

Autore CNR

• WERNER OBERHAUSER (Unità di personale interno)

Insieme di parole chiave

• Keywords of "First true square-planar Hg(II) compound: synthesis and full characterization of trans-(Hg(Ph2PNP(O)Ph2-P,O)2" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute of chemistry of organometallic compounds (ICCOM) (Istituto)

Autore CNR di

• WERNER OBERHAUSER (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganic chemistry communications (Rivista)

Insieme di parole chiave di

• Keywords of "First true square-planar Hg(II) compound: synthesis and full characterization of trans-(Hg(Ph2PNP(O)Ph2-P,O)2" (Insieme di parole chiave)