Synthesis of a New Enantiopure Bicyclic gamma/delta-Amino Acid (btka) Derived from Tartaric Acid and a-Amino Acetopheno (Articolo in rivista)

Type
Label
  • Synthesis of a New Enantiopure Bicyclic gamma/delta-Amino Acid (btka) Derived from Tartaric Acid and a-Amino Acetopheno (Articolo in rivista) (literal)
Anno
  • 2002-01-01T00:00:00+01:00 (literal)
Alternative label
  • Guarna A., Bucelli I., Machetti F., Menchi G., Occhiato E. G., Trabocchi A. (2002)
    Synthesis of a New Enantiopure Bicyclic gamma/delta-Amino Acid (btka) Derived from Tartaric Acid and a-Amino Acetopheno
    in Tetrahedron (Oxf., Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Guarna A., Bucelli I., Machetti F., Menchi G., Occhiato E. G., Trabocchi A. (literal)
Pagina inizio
  • 9865 (literal)
Pagina fine
  • 9870 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 58 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Titolo
  • Synthesis of a New Enantiopure Bicyclic gamma/delta-Amino Acid (btka) Derived from Tartaric Acid and a-Amino Acetopheno (literal)
Abstract
  • The synthesis of a novel enantiopure gamma/delta-amino acid having the 3- aza-6,8- dioxabicyclo[3.2.1]octane structure was realized by the combination of tartaric acid derivatives and alfa-amino acetophenone followed by a trans- acetalisation process. This amino acid, which has a rigid skeleton and carries substituents at the 3, 5 and 7 positions of the scaffold, could find different applications in organic and peptidomimetic synthesis. Two different synthetic strategies were studied, one of them allowing the multigram scale preparation of the amino acid. (literal)
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