Expanding the scope of atropisomeric monodentate P-donor ligands in asymmetric catalysis. Asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl-1-esters by Pd/ BINEPINE catalysts (Articolo in rivista)

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  • Expanding the scope of atropisomeric monodentate P-donor ligands in asymmetric catalysis. Asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl-1-esters by Pd/ BINEPINE catalysts (Articolo in rivista) (literal)
Anno
  • 2010-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.tetasy.2010.04.031 (literal)
Alternative label
  • Alberico E.; Gladiali S.; Taras R.; Junge K.; Beller M.; (2010)
    Expanding the scope of atropisomeric monodentate P-donor ligands in asymmetric catalysis. Asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl-1-esters by Pd/ BINEPINE catalysts
    in Tetrahedron: asymmetry (Print); Pergamon-Elsevier Science Ltd., Oxford (Regno Unito)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Alberico E.; Gladiali S.; Taras R.; Junge K.; Beller M.; (literal)
Pagina inizio
  • 1406 (literal)
Pagina fine
  • 1410 (literal)
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  • Articolo pubblicato in Special Issue \"Henri Kagan: An 80th Birthday Celebration Special Issue - Part 2\". (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://www.sciencedirect.com/science/article/pii/S095741661000279X (literal)
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  • 21 (literal)
Rivista
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  • 11-12 (literal)
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  • Scopu (literal)
  • ISI Web of Science (WOS) (literal)
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  • Istituto di Chimica Biomolecolare, CNR; Università degli Studi di Sassari; Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany. (literal)
Titolo
  • Expanding the scope of atropisomeric monodentate P-donor ligands in asymmetric catalysis. Asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl-1-esters by Pd/ BINEPINE catalysts (literal)
Abstract
  • Monodentate binaphthophosphepines (BINEPINES) have been tested in the palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenylallyl esters. Stereoselectivities of up to 92% ee have been achieved in the alkylation of the acetate ester with the C-nucleophile, generated in situ by the action of BSA (N,Obis( trimethylsilyl)acetamide) on dimethylmalonate in the presence of a catalytic amount of sodium acetate. (literal)
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