Isolation and structural elucidation of eight new related analogues of the mycotoxin (-)-botryodiplodin from Penicillium coalescens. (Articolo in rivista)

Type
Label
  • Isolation and structural elucidation of eight new related analogues of the mycotoxin (-)-botryodiplodin from Penicillium coalescens. (Articolo in rivista) (literal)
Anno
  • 2007-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/jf071568v (literal)
Alternative label
  • N. Cabedo, M. P. Lopez-Gresa, J. Primo, M. L. Ciavatta, M. C. Gonzalez (2007)
    Isolation and structural elucidation of eight new related analogues of the mycotoxin (-)-botryodiplodin from Penicillium coalescens.
    in Journal of agricultural and food chemistry
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • N. Cabedo, M. P. Lopez-Gresa, J. Primo, M. L. Ciavatta, M. C. Gonzalez (literal)
Pagina inizio
  • 6977 (literal)
Pagina fine
  • 6983 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 55 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Centro de Ecolog?´a Qu?´mica Agr?´cola, Universidad Polite´cnica de Valencia, Campus de Vera, Edificio 9B, Laboratorio 111, 46022 Valencia, Spain, Istituto per la Chimica Biomolecolare, CNR, Via Campi Flegrei 34, 80078 Pozzuoli, Italy, and Instituto Valenciano de Investigaciones Agrarias, Centro de Citricultura y Produccio´n Vegetal, Carretera Na´quera-Moncada, Km. 4.5, 46113 Moncada, Valencia, Spain (literal)
Titolo
  • Isolation and structural elucidation of eight new related analogues of the mycotoxin (-)-botryodiplodin from Penicillium coalescens. (literal)
Abstract
  • Bioassay-guided fractionation of the organic extract derived from the terrestrial fungus Penicillium coalescens led to the isolation of the known mycotoxin (-)-botryodiplodin (1) and eight new structurally related analogues (2-9). The structures of the novel compounds were determined by MS and NMR studies, including 1D and 2D NMR. A likely biogenetic pathway from the aldehydic open form of 1 (C7 unit, U1) is proposed for these metabolites. Among all the isolated metabolites, only (-)-1 showed antifungal, antibacterial, and insecticidal activity. This latter activity appears to be a new property attributed to (-)-1. (literal)
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