Stereospecific palladium(0)-catalyzed reduction of 2-cyclobutylidenepropyl esters: A versatile preparation of diastereomeric monoterpenoids: (±)-Fragranol and (±)-Grandisol (Articolo in rivista)

Type
Label
  • Stereospecific palladium(0)-catalyzed reduction of 2-cyclobutylidenepropyl esters: A versatile preparation of diastereomeric monoterpenoids: (±)-Fragranol and (±)-Grandisol (Articolo in rivista) (literal)
Anno
  • 2003-01-01T00:00:00+01:00 (literal)
Alternative label
  • Bernard, A.M.; Frongia, A.; Secci, F.; Delogu, G.; Ollivier, J.; Piras, P.P.; Salaun, J. (2003)
    Stereospecific palladium(0)-catalyzed reduction of 2-cyclobutylidenepropyl esters: A versatile preparation of diastereomeric monoterpenoids: (±)-Fragranol and (±)-Grandisol
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Bernard, A.M.; Frongia, A.; Secci, F.; Delogu, G.; Ollivier, J.; Piras, P.P.; Salaun, J. (literal)
Pagina inizio
  • 9433 (literal)
Pagina fine
  • 9440 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 59 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Titolo
  • Stereospecific palladium(0)-catalyzed reduction of 2-cyclobutylidenepropyl esters: A versatile preparation of diastereomeric monoterpenoids: (±)-Fragranol and (±)-Grandisol (literal)
Abstract
  • Mixture of (E and Z)-2-cyclobutylidenepropyl sulfonates, readily available from alfa,alfa-disubstituted cyclobutanes arising from suitable cyclopropane derivatives ring expansion, underwent regioselective and stereospecific reduction by formate anion to offer, through pi-greco 1,1-trimethyleneallylpalladium complexes formed upon treatment with palladium(0), a new and convenient entry to the diastereomeric four-membered ring monoterpenoids racemica fragranol and racemic grandisol. (literal)
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