Readily available carbohydrate-derived imines and amides as chiral ligands for asymmetric (Articolo in rivista)

Type
Label
  • Readily available carbohydrate-derived imines and amides as chiral ligands for asymmetric (Articolo in rivista) (literal)
Anno
  • 2002-01-01T00:00:00+01:00 (literal)
Alternative label
  • Pigro M.C., Angiuoni G., Piancatelli G. (2002)
    Readily available carbohydrate-derived imines and amides as chiral ligands for asymmetric
    in Tetrahedron (Oxf., Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Pigro M.C., Angiuoni G., Piancatelli G. (literal)
Pagina inizio
  • 5459 (literal)
Pagina fine
  • 5466 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 58 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Titolo
  • Readily available carbohydrate-derived imines and amides as chiral ligands for asymmetric (literal)
Abstract
  • An easy and diastereoselective strategy for the synthesis of a new tetrahydrofuranic chiral aldehyde and a new tetrahydrofuranic acid derived from D-ribose is reported. These compounds have been shown to be useful starting materials for obtaining a never described before class of iminic- and amidic-carbohydrate based chiral ligands, endowed with stability to purification on silica flash column and to storage, and characterized by the presence of a stereogenic center alpha to the iminic or amidic bond. The first results obtained from the application of these chiral ligands in a model reaction, conjugate addition of Et2Zn to cyclohexenone, are discussed (literal)
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