http://www.cnr.it/ontology/cnr/individuo/prodotto/ID14670
Readily available carbohydrate-derived imines and amides as chiral ligands for asymmetric (Articolo in rivista)
- Type
- Label
- Readily available carbohydrate-derived imines and amides as chiral ligands for asymmetric (Articolo in rivista) (literal)
- Anno
- 2002-01-01T00:00:00+01:00 (literal)
- Alternative label
Pigro M.C., Angiuoni G., Piancatelli G. (2002)
Readily available carbohydrate-derived imines and amides as chiral ligands for asymmetric
in Tetrahedron (Oxf., Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Pigro M.C., Angiuoni G., Piancatelli G. (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Note
- ISI Web of Science (WOS) (literal)
- Titolo
- Readily available carbohydrate-derived imines and amides as chiral ligands for asymmetric (literal)
- Abstract
- An easy and diastereoselective strategy for the synthesis of a new
tetrahydrofuranic chiral aldehyde and a new tetrahydrofuranic acid
derived from D-ribose is reported. These compounds have been shown to be
useful starting materials for obtaining a never described before class of
iminic- and amidic-carbohydrate based chiral ligands, endowed with
stability to purification on silica flash column and to storage, and
characterized by the presence of a stereogenic center alpha to the iminic
or amidic bond. The first results obtained from the application of these
chiral ligands in
a model reaction, conjugate addition of Et2Zn to cyclohexenone, are
discussed
(literal)
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