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The simultaneous separation of different enantiomeric pairs in capillary electrophoresis by mixing different hemispherodextrins, a very versatile class of receptors (Articolo in rivista)
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- Label
- The simultaneous separation of different enantiomeric pairs in capillary electrophoresis by mixing different hemispherodextrins, a very versatile class of receptors (Articolo in rivista) (literal)
- Anno
- 2002-01-01T00:00:00+01:00 (literal)
- Alternative label
Cucinotta V., Giuffrida A., Grasso G., Maccarrone G., Messina M. (2002)
The simultaneous separation of different enantiomeric pairs in capillary electrophoresis by mixing different hemispherodextrins, a very versatile class of receptors
in Journal of chromatography (Print)
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- Cucinotta V., Giuffrida A., Grasso G., Maccarrone G., Messina M. (literal)
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- Titolo
- The simultaneous separation of different enantiomeric pairs in capillary electrophoresis by mixing different hemispherodextrins, a very versatile class of receptors (literal)
- Abstract
- Six different racemates of the profen family were used as analytes in
order to test the properties of chiral selectors of the three members of a
new class of cyclodextrin derivatives called hemispherodextrins (HMs) in
capillary electrophoresis. Besides experiments carried out to separate
each enantiomeric pair one by one, other experiments were carried out on
samples containing all the six enantiomeric pairs together.
Electropherograms were obtained either by adding a single HM to BGE, or a
binary mixture of HMs. The results obtained confirm the excellent
properties of chiral selectivity of HMs, and furthermore show that these
compounds can be used for achiral selection too. When mixing different
HMs, a sort of complementary effect in chiral selectivity is observed,
which, in our opinion, deserves further study. (literal)
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