http://www.cnr.it/ontology/cnr/individuo/prodotto/ID1312
Combination of microstructuring and laser-light irradiation for the reversible wettability of photosensitised polymer surfaces (Articolo in rivista)
- Type
- Label
- Combination of microstructuring and laser-light irradiation for the reversible wettability of photosensitised polymer surfaces (Articolo in rivista) (literal)
- Anno
- 2006-01-01T00:00:00+01:00 (literal)
- Alternative label
Athanassiou, A; Varda, M; Mele, E; Lygeraki, MI; Pisignano, D; Farsari, M; Fotakis, C; Cingolani, R; Anastasiadis, SH (2006)
Combination of microstructuring and laser-light irradiation for the reversible wettability of photosensitised polymer surfaces
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Athanassiou, A; Varda, M; Mele, E; Lygeraki, MI; Pisignano, D; Farsari, M; Fotakis, C; Cingolani, R; Anastasiadis, SH (literal)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Fdn Res & Technol Hellas, Inst Elect Struct & Laser, Iraklion 71110, Crete, Greece; Univ Crete, Dept Phys, Iraklion 71003, Crete, Greece; CNR, Natl Nanotechnol Lab, I-73100 Lecce, Italy; Univ Patras, Dept Phys, Patras 22500, Greece (literal)
- Titolo
- Combination of microstructuring and laser-light irradiation for the reversible wettability of photosensitised polymer surfaces (literal)
- Abstract
- The wetting characteristics of surfaces of polymers doped with photochromic spiropyran molecules can be tuned when irradiated with laser beams of properly chosen photon energy. In particular, UV laser pulses at 308 nm are responsible for the enhancement of the hydrophilicity of the surfaces, since the embedded non-polar spiropyran molecules convert to their polar merocyanine isomers upon UV absorption. The process is reversed upon irradiation with green laser pulses at 532 nm. When the photochromic-polymeric surfaces are micropatterned using soft lithography or photo-polymerisation techniques, they can change their wettability towards a more hydrophobic or more hydrophilic behaviour depending on the dimensions of the patterned features and on the hydrophilicity-hydrophobicity of the flat surface. Furthermore, the light-induced wettability variations on these structured surfaces are greatly enhanced compared to the flat surfaces. This significant increase to the wettability changes is attributed to the combination of the photochromic interconversions upon laser irradiation together with the photoinduced reversible volume changes of the patterned features. (literal)
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