Sulfolobus solfataricus beta-glycosidase catalysed synthesis of sugar alchol conjugates in the presence of organic solvents. (Articolo in rivista)

Type
Label
  • Sulfolobus solfataricus beta-glycosidase catalysed synthesis of sugar alchol conjugates in the presence of organic solvents. (Articolo in rivista) (literal)
Anno
  • 2000-01-01T00:00:00+01:00 (literal)
Alternative label
  • Huneke FU, Bailey D, Nucci R, Cowan D. (2000)
    Sulfolobus solfataricus beta-glycosidase catalysed synthesis of sugar alchol conjugates in the presence of organic solvents.
    in Biocatalysis and biotransformation (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Huneke FU, Bailey D, Nucci R, Cowan D. (literal)
Pagina inizio
  • 291 (literal)
Pagina fine
  • 299 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 18 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Titolo
  • Sulfolobus solfataricus beta-glycosidase catalysed synthesis of sugar alchol conjugates in the presence of organic solvents. (literal)
Abstract
  • The thermostable beta-D-glycosidase from the archaeon Sulfolobus solfataricus was used for the glucosylation of secondary alcohols at high organic solvent concentrations. Alkyl glucoside products were analysed by one- and two-dimensional NMR. Using a range of racemic secondary alcohols and various hydrophilic organic solvents, small but significant substrate- and solvent-dependent changes in the R/S ratios of alkyl glucoside products were detected. The anomeric specificity of the enzyme was apparently affected by butan-2-one. A possible mechanistic model for solvent-induced changes at the active site is presented. (literal)
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