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Disentangling the complex line profiles in the Cl 2p photoelectron spectra of Cl-2 (Articolo in rivista)

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Disentangling the complex line profiles in the Cl 2p photoelectron spectra of Cl-2 (Articolo in rivista) (literal)

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Travnikova, O; Fink, RF; Kivimaki, A; Ceolin, D; Bao, Z; Piancastelli, MN (2006)
Disentangling the complex line profiles in the Cl 2p photoelectron spectra of Cl-2
in Chemical physics letters (Print)
(literal)

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Travnikova, O; Fink, RF; Kivimaki, A; Ceolin, D; Bao, Z; Piancastelli, MN (literal)

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Uppsala Univ, Dept Phys, SE-75121 Uppsala, Sweden; CNR, TASC, INFM, Lab Nazl, I-34012 Trieste, Italy (literal)

Titolo

Disentangling the complex line profiles in the Cl 2p photoelectron spectra of Cl-2 (literal)

Abstract

High-resolution Cl (2p) photoelectron spectra Of Cl-2 are reported and their complex structure is analyzed in detail, taking into account molecular field (NIF), spin-orbit (SO) and parity splitting. High-level ab initio calculations were performed to provide reliable values for spectroscopic parameters. Accurate data analysis enabled us to determine the value of molecular-field splitting of 86 7 meV, and values of 92 5, 79 11 and 105 12 meV for the lifetime line widths of the (2)Pi(1/2), (2)Sigma(+)(1/2) and (2)Pi(3/2) states, respectively. The gerade-ungerade splitting of less than 5 meV is obtained from the calculations. (c) 2006 Elsevier B.V. All rights reserved. (literal)

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