Understanding mixed valent materials: Effects of dynamical core-hole screening in high-pressure x-ray spectroscopy (Articolo in rivista)

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Label
  • Understanding mixed valent materials: Effects of dynamical core-hole screening in high-pressure x-ray spectroscopy (Articolo in rivista) (literal)
Anno
  • 2006-01-01T00:00:00+01:00 (literal)
Alternative label
  • Dallera, C; Wessely, O; Colarieti-Tosti, M; Eriksson, O; Ahuja, R; Johansson, B; Katsnelson, MI; Annese, E; Rueff, JP; Vanko, G; Braicovich, L; Grioni, M (2006)
    Understanding mixed valent materials: Effects of dynamical core-hole screening in high-pressure x-ray spectroscopy
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Dallera, C; Wessely, O; Colarieti-Tosti, M; Eriksson, O; Ahuja, R; Johansson, B; Katsnelson, MI; Annese, E; Rueff, JP; Vanko, G; Braicovich, L; Grioni, M (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 74 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Politecn Milan, Dipartimento Fis, INFM, I-20133 Milan, Italy; Uppsala Univ, Dept Phys, Uppsala, Sweden; Linkoping Univ, Dept Phys Chem & Biol, S-58183 Linkoping, Sweden; Radboud Univ Nijmegen, Inst Mol & Mat, NL-6525 ED Nijmegen, Netherlands; Univ Modena, Dipartimento Fis, INFM, I-41100 Modena, Italy; Synchrotron SOLEIL, F-91192 Gif Sur Yvette, France; European Synchrotron Radiat Facil, F-38043 Grenoble, France; Ecole Polytech Fed Lausanne, IPN, CH-1015 Lausanne, Switzerland; Univ Paris 06, Lab Chim Phys Mat & Rayonnement, UMR 7614, F-75231 Paris 05, France (literal)
Titolo
  • Understanding mixed valent materials: Effects of dynamical core-hole screening in high-pressure x-ray spectroscopy (literal)
Abstract
  • Changes in the electronic structure of Yb, a material whose valence is modified under pressure, are observed with remarkable detail in x-ray absorption and emission data measured between ambient conditions and 20 GPa. These changes are reproduced by a theory that essentially does not rely on experimental parameters, and includes dynamical core-hole screening. From the combined experimental and theoretical data we can firmly establish on a quantitative level how the valency of an intermediate valence material is modified by pressure. In metallic Yb it increases from 2 to 2.55 +/- 0.05 between 0 and 20 GPa. (literal)
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