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A possible mechanism underlying the anpmalous dielectric response in concentrated methanol-in-carbon tetrachloride mixtures (Articolo in rivista)
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- A possible mechanism underlying the anpmalous dielectric response in concentrated methanol-in-carbon tetrachloride mixtures (Articolo in rivista) (literal)
- Anno
- 2007-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1478/C1A0701002 (literal)
- Alternative label
Pieruccini M. , Saija F. (2007)
A possible mechanism underlying the anpmalous dielectric response in concentrated methanol-in-carbon tetrachloride mixtures
in Atti della Accademia Peloritana dei Pericolanti. Classe di Scienze Fisiche, Matematiche e Naturali (Online); Accademia Peloritana dei Pericolanti, Messina (Italia)
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- Pieruccini M. , Saija F. (literal)
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- Istituto Processi Chimico-Fisici, Messina (Italy) (literal)
- Titolo
- A possible mechanism underlying the anpmalous dielectric response in concentrated methanol-in-carbon tetrachloride mixtures (literal)
- Abstract
- The association of CCl4 with the non-donating ends of open (chain-like)
methanol aggregates, is shown to be relevant in the occurrence of positive deviations of
the static dielectric constant with respect to ideality in methanol/CCl4 mixtures. This interaction
tends to reduce in fact the fraction of methanol aggregated in cyclic clusters.
This hypothesis is suggested by the comparison with the data of lattice calculations for the
equilibrium distribution of methanol clusters. (literal)
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