Propagation of spin information at supra-molecular scale through hetero-aromatic linkers (Articolo in rivista)

Type
Label
  • Propagation of spin information at supra-molecular scale through hetero-aromatic linkers (Articolo in rivista) (literal)
Anno
  • 2011-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1103/PhysRevLett.106.227205 (literal)
Alternative label
  • V. Bellini; G. Lorusso; A. Candini; W. Wernsdorfer; T.B. Faust; G.A. Timco; R.E.P. Winpenny; M. Affronte (2011)
    Propagation of spin information at supra-molecular scale through hetero-aromatic linkers
    in Physical review letters (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • V. Bellini; G. Lorusso; A. Candini; W. Wernsdorfer; T.B. Faust; G.A. Timco; R.E.P. Winpenny; M. Affronte (literal)
Pagina inizio
  • 227205 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 106 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
  • DOI: 10.1103/PhysRevLett.106.227205 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • S3-Institute Nanoscience-CNR, Via Campi 213/A, 41125 Modena, Italy Laboratoire Louis Néel, avenue des Martyres 24, Grenoble, France School of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, United Kingdom The Photon Science Institute, The University of Manchester, Oxford Road, Manchester, M13 9PL, United Kingdom Dipartimento di Fisica, Universitá di Modena e Reggio Emilia, Via Campi 213/A, 41125 Modena, Italy (literal)
Titolo
  • Propagation of spin information at supra-molecular scale through hetero-aromatic linkers (literal)
Abstract
  • We report an in-depth study on how spin information propagates at supramolecular scale through a family of heteroaromatic linkers. By density-functional theory calculations, we rationalize the behavior of a series of Cr7Ni dimers for which we are able to systematically change the aromatic linker thus tuning the strength of the magnetic interaction, as experimentally shown by low temperature micro-SQUID and specific heat measurements. We also predict a cosa2 dependence of the magnetic coupling on the twisting angle between the aromatic cycles in bicyclic linkers, a mechanism parallel to charge transport on similar systems [ L. Venkataraman et al. Nature (London) 442 904 (2006)]. (literal)
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