Dopamine Adsorption on Anatase TiO2(101): A Photoemission and NEXAFS Spectroscopy Study (Articolo in rivista)

Type
Label
  • Dopamine Adsorption on Anatase TiO2(101): A Photoemission and NEXAFS Spectroscopy Study (Articolo in rivista) (literal)
Anno
  • 2010-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/la1016092 (literal)
Alternative label
  • Syres, K.; Thomas, A.; Bondino, F.; Malvestuto, M.; Gratzel, M. (2010)
    Dopamine Adsorption on Anatase TiO2(101): A Photoemission and NEXAFS Spectroscopy Study
    in Langmuir
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Syres, K.; Thomas, A.; Bondino, F.; Malvestuto, M.; Gratzel, M. (literal)
Pagina inizio
  • 14548 (literal)
Pagina fine
  • 14555 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 26 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
  • Scopu (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • School of Physics and Astronomy, The Photon Science Institute, Alan Turing Building, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K., IOM CNR, Laboratorio TASC, Strada Statale 14, Km. 163,5, I-34149 Basovizza, Trieste, Italy, Sincrotrone Trieste S.CpA di Interesse Nazionale, Strada Statale, 14 Km. 163,5 in Area Science Park, 34149 Basovizza, Trieste, Italy, Laboratory of Photonics and Interfaces, Institute of Chemical Science and Engineering, Faculty of Basic Science, Ecole Polytechnique Federale de Lausanne, CH-1015 Lausanne, Switzerland (literal)
Titolo
  • Dopamine Adsorption on Anatase TiO2(101): A Photoemission and NEXAFS Spectroscopy Study (literal)
Abstract
  • The adsorption of dopamine onto an anatase TiO2(101) single crystal has been studied using photoemission and NEXAFS techniques. Photoemission results suggest that the dopamine molecule adsorbs on the surface in a bidentate geometry, resulting in the removal of band gap states in the TiO2 valence band. Using the searchlight effect, carbon K-edge NEXAFS spectra indicate that the phenyl rings in the dopamine molecules are orientated normal to the surface. A combination of experimental and computational results indicates the appearance of new unoccupied states arising following adsorption. The possible role of these states in the charge-transfer mechanism of the dopamine-TiO2 system is discussed. (literal)
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