http://www.cnr.it/ontology/cnr/individuo/prodotto/ID58660
Dopamine Adsorption on Anatase TiO2(101): A Photoemission and NEXAFS Spectroscopy Study (Articolo in rivista)
- Type
- Label
- Dopamine Adsorption on Anatase TiO2(101): A Photoemission and NEXAFS Spectroscopy Study (Articolo in rivista) (literal)
- Anno
- 2010-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1021/la1016092 (literal)
- Alternative label
Syres, K.; Thomas, A.; Bondino, F.; Malvestuto, M.; Gratzel, M. (2010)
Dopamine Adsorption on Anatase TiO2(101): A Photoemission and NEXAFS Spectroscopy Study
in Langmuir
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Syres, K.; Thomas, A.; Bondino, F.; Malvestuto, M.; Gratzel, M. (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Note
- ISI Web of Science (WOS) (literal)
- Scopu (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- School of Physics and Astronomy, The Photon Science Institute, Alan Turing Building, The University of
Manchester, Oxford Road, Manchester M13 9PL, U.K.,
IOM CNR, Laboratorio TASC, Strada Statale 14, Km. 163,5, I-34149 Basovizza, Trieste, Italy,
Sincrotrone Trieste S.CpA di Interesse Nazionale, Strada Statale, 14 Km. 163,5 in Area Science Park, 34149 Basovizza, Trieste, Italy,
Laboratory of Photonics and Interfaces, Institute of Chemical Science and Engineering, Faculty of Basic Science, Ecole Polytechnique
Federale de Lausanne, CH-1015 Lausanne, Switzerland (literal)
- Titolo
- Dopamine Adsorption on Anatase TiO2(101): A Photoemission and NEXAFS Spectroscopy Study (literal)
- Abstract
- The adsorption of dopamine onto an anatase TiO2(101) single crystal has been studied using photoemission and
NEXAFS techniques. Photoemission results suggest that the dopamine molecule adsorbs on the surface in a bidentate
geometry, resulting in the removal of band gap states in the TiO2 valence band. Using the searchlight effect, carbon
K-edge NEXAFS spectra indicate that the phenyl rings in the dopamine molecules are orientated normal to the surface.
A combination of experimental and computational results indicates the appearance of new unoccupied states arising
following adsorption. The possible role of these states in the charge-transfer mechanism of the dopamine-TiO2 system
is discussed. (literal)
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- Autore CNR
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