Variable Photon Energy Photoelectron Spectroscopy and Magnetism of YbCp3 and LuCp3 (Articolo in rivista)

Type
Label
  • Variable Photon Energy Photoelectron Spectroscopy and Magnetism of YbCp3 and LuCp3 (Articolo in rivista) (literal)
Anno
  • 2010-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/om100240m (literal)
Alternative label
  • Coreno, Marcello a; de Simone, Monica b; Coates, Rosemary c; Denning, Mark S. d; Denning, Robert G. d; Green, Jennifer C. d; Hunston, Charlene c; Kaltsoyannis, Nikolas c; Sella, Andrea c (2010)
    Variable Photon Energy Photoelectron Spectroscopy and Magnetism of YbCp3 and LuCp3
    in Organometallics
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Coreno, Marcello a; de Simone, Monica b; Coates, Rosemary c; Denning, Mark S. d; Denning, Robert G. d; Green, Jennifer C. d; Hunston, Charlene c; Kaltsoyannis, Nikolas c; Sella, Andrea c (literal)
Pagina inizio
  • 4752 (literal)
Pagina fine
  • 4755 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 29 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 21 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • a CNR-IMIP, GasPhase Beamline@Elettra and Monterotondo, 00016 Roma, Italy, b CNR-IOM, Laboratorio TASC, 34149 Trieste, Italy c Department of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ, U.K., d Department of Chemistry, Oxford University, South Parks Road, Oxford OX1 3QR, U.K. (literal)
Titolo
  • Variable Photon Energy Photoelectron Spectroscopy and Magnetism of YbCp3 and LuCp3 (literal)
Abstract
  • The first examples of gas-phase photoelectron spectra of ytterbium and lutetium complexes are reported. Variable photon energy photoelectron spectroscopy of YbCp3 (Cp=?-C5H5) shows that f electron ionization gives ion states corresponding to both 4f12 and 4f13 configurations, whereas that of LuCp3 reveals only 4f13 ion states. Magnetic data on crystalline YbCp3 display Curie behavior between 20 and 305 K with a magnetic moment of 3.53 ?B. Both the photoelectron spectra and the magnetic moment are consistent with the proposal that YbCp3 has a mixed configuration ground state with the unpaired spin residing both in an f orbital and on the cyclopentadienyl ligands. (literal)
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