http://www.cnr.it/ontology/cnr/individuo/prodotto/ID58350
Polysynthetic nature of stage-one graphite-metal intercalation compounds prepared from graphite single crystals (Articolo in rivista)
- Type
- Label
- Polysynthetic nature of stage-one graphite-metal intercalation compounds prepared from graphite single crystals (Articolo in rivista) (literal)
- Anno
- 2010-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1103/PhysRevB.81.155425 (literal)
- Alternative label
Lagrange, P; Cahen, S; Emery, N; Herold, C; Rida, H; Mareche, JF; Lamura, G (2010)
Polysynthetic nature of stage-one graphite-metal intercalation compounds prepared from graphite single crystals
in Physical review. B, Condensed matter and materials physics; APS, American physical society, College Park, MD (Stati Uniti d'America)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Lagrange, P; Cahen, S; Emery, N; Herold, C; Rida, H; Mareche, JF; Lamura, G (literal)
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- ISI Web of Science (WOS) (literal)
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- P. Lagrange; S. Cahen; N. Emery; C. Hérold; H. Rida; J. F. Marêché; G. Lamura (literal)
- Titolo
- Polysynthetic nature of stage-one graphite-metal intercalation compounds prepared from graphite single crystals (literal)
- Abstract
- In this paper we address the mechanism of intercalation of commensurate metal-graphite intercalation
compounds and its consequences on the structural properties of the synthesized materials. Using the case of
KC8 which crystallizes in the orthorhombic system ?Fddd space group? and consequently does not possess any
hexagonal or rhombohedral symmetries, it has been possible to show that a KC8 sample prepared from a
natural graphite single crystal however exhibits experimentally an hexagonal symmetry. This apparent irratio-
nal observation is fully explained in this paper by the intercalation process itself so that after intercalation the
compound is no more a single crystal. This result is extended to the cases of all the first stage metal-graphite
intercalation compounds. (literal)
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