http://www.cnr.it/ontology/cnr/individuo/prodotto/ID57272
Combined vibrational spectra of natural wardite (Articolo in rivista)
- Type
- Label
- Combined vibrational spectra of natural wardite (Articolo in rivista) (literal)
- Anno
- 2004-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.molstruc.2004.01.039 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Breitinger D. K. (a); Belz H.-H. (b); Hajba L. (c); Komlósi V. (c); Mink J. (c); Brehm G. (d); Colognesi D. (e)*; Parker S. F. (e); Schwab R. G. (f) (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni
- Studies in the vibrational spectroscopy of inorganic materials - A collection of invited papers in honour of Professor Heinz-Dieter Lutz on the occasion of his 70th birthday. (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
- http://www.sciencedirect.com/science/article/pii/S0022286004000857 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
- fasc. (1-3). Elsevier.
Studies in the vibrational spectroscopy of inorganic materials - A collection of invited papers in honour of Professor Heinz-Dieter Lutz on the occasion of his 70th birthday. (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- (a) Institute of Inorganic Chemistry, University of Erlangen-Nuernberg, Egerlandstrasse 1, D-91058 Erlangen, Germany
(b) Thermo Electron, Im Steingrund 4-6, D-63303 Dreieich, Germany
(c) Chemical Research Center of the Hungarian Academy of Sciences, Molecular Spectroscopy Department, P O Box 17, H-1525 Budapest, Hungary
(d) Institute of Physical Chemistry, Egerlandstrasse 3, D-91058 Erlangen, Germany
(e) Rutherford Appleton Laboratory, Chilton, Didcot, OX11 OQX, UK
(f) Institute of Geology and Mineralogy, Schlossgarten 5a, D-91054 Erlangen, Germany (literal)
- Titolo
- Combined vibrational spectra of natural wardite (literal)
- Abstract
- Vibrational spectra (IR, Raman, inelastic neutron scattering) were measured of natural wardite (ideal formula NaAl3(OH)4(PO4)2·2 H2O) from Trauira, Brazil, with the main impurities Fe and Ca. The spectra are discussed on the basis of a symmetry analysis restricted to one layer in the four-layer structure. The band pattern in the n(OH) region is due to two different Al2OH groups and their correlation coupling; their
deformations d and g are assigned based on IR and INS spectra. Contributions of the hydrogen-bonded H2O molecules are discussed, as are the vibrations of the AlO6 octahedra dominating the Raman spectrum. From the fundamentals n(OH) of the OH groups and their overtones anharmonicity constants have been estimated. (literal)
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