http://www.cnr.it/ontology/cnr/individuo/prodotto/ID55618
Catalytic features of Rh and Ni supported catalysts in the steam reforming of glycerol to produce hydrogen (Articolo in rivista)
- Type
- Label
- Catalytic features of Rh and Ni supported catalysts in the steam reforming of glycerol to produce hydrogen (Articolo in rivista) (literal)
- Anno
- 2010-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.apcata.2010.03.039 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- V. Chiodo(a); S. Freni(a); A. Galvagno (b); N. Mondello(a); F. Frusteri(a) (literal)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
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- Google Scholar (literal)
- ISI Web of Science (WOS) (literal)
- Scopus (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- a) CNR-ITAE \"Nicola Giordano\", Via S. Lucia sopra Contesse, 5-98126 - Messina, Italy
b) DIIM, Università degli Studi di Catania, Viale A. Doria, 6-95125 - Catania, Italy (literal)
- Titolo
- Catalytic features of Rh and Ni supported catalysts in the steam reforming of glycerol to produce hydrogen (literal)
- Abstract
- Glycerol steam reforming on Rh and Ni supported catalyst was investigate in view to produce syn-gas to
feed a high temperature fuel cell system (SOFC-MCFC). Results obtained revealed that glycerol is subjected
to pyrolysis phenomena and at temperature higher than 720K drastically decomposes before to reach
the catalyst surface. Rh/Al2O3 catalyst resulted to be more active and stable than Ni supported catalysts
but independently from the catalyst used (Rh or Ni) and temperature investigated, the reaction is affected
by coke formation mainly promoted by the large presence of olefins formed by glycerol thermal decomposition.
Even if for thermodynamic reasons the hydrogen production should be favored by operating
at high temperature, results obtained demonstrate that it is more convenient to operate at temperature
not higher than 923 K, since higher reaction temperature promotes the formation of encapsulated carbon
which negatively reflects on catalyst stability. (literal)
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- Autore CNR
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